Abstract:
Tris(2-pyridyl)phosphine chalcogenides Py3P=X (X = O, S, Se) react with PdCl2 or Li2PdCl4 to give the chelate complexes cis-[Pd(N,N’-Py3P=X)Cl2] in which PdII ion is square-planar coordinated to two pyridine nitrogen atoms of the ligand (κ2-N,N’).
Citation:
A. V. Artem'ev, N. K. Gusarova, S. F. Malysheva, N. A. Belogorlova, O. N. Kazheva, G. G. Alexandrov, O. A. Dyachenko, B. A. Trofimov, “Unexpected N,N’-coordination of tris(2-pyridyl)-phosphine chalcogenides to PdCl2”, Mendeleev Commun., 25:3 (2015), 196–198
Linking options:
https://www.mathnet.ru/eng/mendc2348
https://www.mathnet.ru/eng/mendc/v25/i3/p196
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