Abstract:
The Chapman rearrangement of aryl N-arylbenzimidates to tertiary acyclic amides is accelerated in ionic liquids and proceeds at lower temperatures as 120–190°C.
Document Type:
Article
Language: English
Citation:
M. A. Epishina, A. S. Kulikov, N. V. Ignat'ev, M. Schulte, N. N. Makhova, “Efficient synthesis of tertiary acyclic amides by the Chapman rearrangement of aryl benzimidates in ionic liquids”, Mendeleev Commun., 25:2 (2015), 126–128
Linking options:
https://www.mathnet.ru/eng/mendc2322
https://www.mathnet.ru/eng/mendc/v25/i2/p126
This publication is cited in the following 6 articles:
Damiano Tanini, Tommaso Pecchi, Nikolai Ignat'ev, Antonella Capperucci, “Ionic Liquids-Assisted Ring Opening of Three-Membered Heterocycles with Thio- and Seleno-Silanes”, Catalysts, 12:10 (2022), 1259
M. G. Chernysheva, A. E. Averina, O. A. Soboleva, G. A. Badun, “Radionuclide and tensiometry approaches to studying lysozyme behaviors in water–ionic liquid systems”, Mendeleev Commun., 27:3 (2017), 296–298
S. V. Savilov, A. O. Artemova, A. S. Ivanov, Z. Shen, S. M. Aldoshin, V. V. Lunin, “Stability of a high-voltage ionic liquid with a substituted piperidinium cation and a TFSI anion, promising for electrochemical applications”, Mendeleev Commun., 26:3 (2016), 240–242
Margarita A. Epishina, Alexander S. Kulikov, Nikolai V. Ignat'ev, Michael Schulte, Nina N. Makhova, “ChemInform Abstract: Efficient Synthesis of Tertiary Acyclic Amides by the Chapman Rearrangement of Aryl Benzimidates in Ionic Liquids.”, ChemInform, 46:33 (2015)