Abstract:
Monoclinic and triclinic modifications of nitrosonium nitratonickelate NO[Ni(NO3)3] as well as triclinic modification of nitrosonium nitratocobaltate NO[Co(NO3)3] (isostructural to triclinic NO[Ni(NO3)3]) have been synthesized by a new synthetic approach. Single crystal XRD studies revealed the similarity of all these structures in which octahedrally coordinated metal atoms are connected through NO3- bridges forming three-dimensional distorted cubic framework with NO+ cations located in the framework cavities.
Document Type:
Article
Language: English
Citation:
E. B. Deeva, A. V. Merkulova, S. I. Troyanov, M. A. Zakharov, V. A. Tafeenko, V. F. Kozlovskii, I. V. Morozov, “Nitrosonium nitratometallates NO[M(NO3)3] (M = Co, Ni): new synthetic approach and crystal structures”, Mendeleev Commun., 26:5 (2016), 421–422
Linking options:
https://www.mathnet.ru/eng/mendc2234
https://www.mathnet.ru/eng/mendc/v26/i5/p421
This publication is cited in the following 3 articles:
A. Vorobyova, I. Danilovich, I. Morozov, Y. Ovchenkov, A. Vasiliev, O. Volkova, A. Iqbal, B. Rahaman, T. Saha-Dasgupta, “Square lattice antiferromagnets (NO)M(NO3)3 (M = Co, Ni): Effects of anisotropy”, Journal of Alloys and Compounds, 929 (2022), 167197
I. L. Danilovich, E. B. Deeva, K. Y. Bukhteev, A. A. Vorobyova, I. V. Morozov, O. S. Volkova, E. A. Zvereva, O. V. Maximova, I. V. Solovyev, S. A. Nikolaev, D. Phuyal, M. Abdel-Hafiez, Y. C. Wang, J.-Y. Lin, J. M. Chen, D. I. Gorbunov, K. Puzniak, B. Lake, A. N. Vasiliev, “Co(NO3)2
as an inverted umbrella-type chiral noncoplanar ferrimagnet”, Phys. Rev. B, 102:9 (2020)
Evgeniya B. Deeva, Anna V. Merkulova, Sergey I. Troyanov, Maxim A. Zakharov, Viktor A. Tafeenko, Vadim F. Kozlovskii, Igor V. Morozov, “ChemInform Abstract: Nitrosonium Nitratometallates NO[M(NO3)3] (M: Co, Ni): New Synthetic Approach and Crystal Structures”, ChemInform, 47:50 (2016)