Abstract:
Ecologically friendly transformation of readily accessible plant allylpolyalkoxybenzenes to hardly available aminotetraalkoxybenzenes has been developed. The efficacy of hydrogenation stage is substantially increased by the application of highly porous ceramic block Pd-catalysts featuring a large surface area, low hydraulic resistance, significant thermal and mechanical stabililty, multiple cycling and easy regeneration.
Citation:
I. B. Karmanova, S. I. Firgang, L. D. Konyushkin, V. N. Khrustalev, A. V. Ignatov, L. A. Kuznetsov, Yu. A. Pinchuk, I. A. Kozlov, V. V. Semenov, “Dill and parsley seed extracts in scale up synthesis of aminopolyalkoxybenzenes – beneficial synthons for fused nitrogen polyalkoxyheterocycles”, Mendeleev Commun., 26:1 (2016), 66–68
Linking options:
https://www.mathnet.ru/eng/mendc2113
https://www.mathnet.ru/eng/mendc/v26/i1/p66
This publication is cited in the following 6 articles:
V. E. Kalugin, O. I. Adaeva, D. V. Demchuk, V. V. Semenov, “Synthesis of new tetraalkoxyquinolines from parsley and dill secondary metabolites”, Mendeleev Commun., 33:4 (2023), 481–483
R. Alan Aitken, Comprehensive Heterocyclic Chemistry IV, 2022, 724
A. E. Varakutin, E. A. Muravsky, I. Yu. Shinkarev, V. N. Khrustalev, V. V. Semenov, “Hydrogenation of plant polyalkoxybenzene derivatives: convenient access to coenzyme Q0 analogues”, Mendeleev Commun., 30:5 (2020), 599–601
A. V. Ignatov, A. E. Varakutin, I. N. Solov'eva, I. B. Karmanova, I. A. Kozlov, M. N. Semenova, V. V. Semenov, “Efficient hydrogenation of benzaldoximes and Schiff bases on ceramic high-porosity palladium catalysts”, Russ Chem Bull, 67:8 (2018), 1394
Ekaterina V. Zaryanova, Alexander A. Ignatov, Nataly A. Lozynskaya, “Synthesis and reactivity of new amide-substituted oxindole derivatives”, Tetrahedron, 73:49 (2017), 6887
R. Alan Aitken, Progress in Heterocyclic Chemistry, 29, 2017, 337