Abstract:
Potassium acetate catalyzed alcoholysis of spirocycloalkyl malonyl peroxides affords 1-alkoxycarbonylcycloalkane-1-percarboxylic acids which are suitable for epoxidation of olefins.
Citation:
M. A. Lapitskaya, V. A. Vil', E. D. Daeva, A. O. Terent'ev, K. K. Pivnitsky, “Alcoholysis of malonyl peroxides to give peracids”, Mendeleev Commun., 26:1 (2016), 14–15
Linking options:
https://www.mathnet.ru/eng/mendc2093
https://www.mathnet.ru/eng/mendc/v26/i1/p14
This publication is cited in the following 7 articles:
Igor V. Alabugin, Leah Kuhn, Michael G. Medvedev, Nikolai V. Krivoshchapov, Vera A. Vil', Ivan A. Yaremenko, Patricia Mehaffy, Meysam Yarie, Alexander O. Terent'ev, Mohammad Ali Zolfigol, “Stereoelectronic power of oxygen in control of chemical reactivity: the anomeric effect is not alone”, Chem. Soc. Rev., 50:18 (2021), 10253
Vera A. Vil', Evgenii S. Gorlov, Bing Yu, Alexander O. Terent'ev, “Oxidative α-acyloxylation of acetals with cyclic diacyl peroxides”, Org. Chem. Front., 8:12 (2021), 3091
Vera A. Vil', Evgenii S. Gorlov, Oleg V. Bityukov, Yana A. Barsegyan, Yulia E. Romanova, Valentina M. Merkulova, Alexander O. Terent'ev, “C-O coupling of Malonyl Peroxides with Enol Ethers via [5+2] Cycloaddition: Non‐Rubottom Oxidation”, Adv Synth Catal, 361:13 (2019), 3173
M. A. Lapitskaya, V. A. Vil', E. D. Daeva, A. O. Terent'ev, K. K. Pivnitsky, “Dimethylmalonoyl peroxide – the neglected lowest homologue: simple synthesis and high reactivity”, Mendeleev Commun., 28:5 (2018), 505–507
Alexander O. Terent'ev, Vera A. Vil', Evgenii S. Gorlov, Olga N. Rusina, Alexander A. Korlyukov, Gennady I. Nikishin, Waldemar Adam, “Selective Oxidative Coupling of 3H‐Pyrazol‐3‐ones, Isoxazol‐5(2H)‐ones, Pyrazolidine‐3,5‐diones, and Barbituric Acids with Malonyl Peroxides: An Effective C‐O Functionalization”, ChemistrySelect, 2:11 (2017), 3334
M. A. Lapitskaya, V. A. Vil', L. L. Vasiljeva, E. D. Daeva, A. O. Terent'ev, K. K. Pivnitsky, “Spontaneous reaction of malonyl peroxides with methanol”, Mendeleev Commun., 27:3 (2017), 243–245
Margarita A. Lapitskaya, Vera A. Vil', Elena D. Daeva, Alexander O. Terent'ev, Kasimir K. Pivnitsky, “ChemInform Abstract: Alcoholysis of Malonyl Peroxides to Give Peracids.”, ChemInform, 47:24 (2016)