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Mendeleev Communications, 2017, Volume 27, Issue 6, Pages 618–620
DOI: https://doi.org/10.1016/j.mencom.2017.11.027
(Mi mendc2079)
 

This article is cited in 22 scientific papers (total in 22 papers)

Communications

Solvent-free Buchwald–Hartwig amination with low palladium loadings

G. A. Chesnokova, P. S. Gribanovb, M. A. Topchiyb, L. I. Minaevac, A. F. Asachenkobc, M. S. Nechaevab, E. V. Bermeshevaad, M. V. Bermeshevb

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
c Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
d I.M. Sechenov First Moscow State Medical University, Moscow, Russian Federation
Abstract: A highly efficient ‘green’ solvent-free monoarylation of primary anilines with aryl bromides mediated by the expanded-ring N-heterocyclic carbene palladium complex (THP-Dipp)Pd(cinn)Cl [THP-Dipp is 1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene; cinn is cinnamyl] can be performed at low catalyst loadings (0.1 mol%) to provide excellent yields and remarkable selectivities for various substrates.
Document Type: Article
Language: English


Citation: G. A. Chesnokov, P. S. Gribanov, M. A. Topchiy, L. I. Minaeva, A. F. Asachenko, M. S. Nechaev, E. V. Bermesheva, M. V. Bermeshev, “Solvent-free Buchwald–Hartwig amination with low palladium loadings”, Mendeleev Commun., 27:6 (2017), 618–620
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  • https://www.mathnet.ru/eng/mendc/v27/i6/p618
  • This publication is cited in the following 22 articles:
    Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
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