A. S. Mendkovich, M. A. Syroeshkin, K. R. Mitina, M. N. Mikhailov, V. P. Gul'tyai, V. M. Pechennikov, “Bond cleavage in hydroxyl derivatives initiated by electron transfer: electroreduction of 9H,9’H-bifluorene-9,9’-diol”, Mendeleev Commun., 27:6 (2017), 580

Abstract: Cyclic voltammetry, digital simulation and quantum chemical methods were applied to study the electroreduction mechanism of vicinal hydroxyl derivatives using 9H,9’H-bifluorene- 9,9’-diol as an example. Unlike the case of fluoren-9-ol, dissociation of the C⁹–C^9’ bond rather than the C⁹–OH one occurs in radical anion of the substrate, similarly to that in radical cations formed upon oxidation of vicinal hydroxyl derivatives.

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