Abstract:
The reaction of 3,3-disubstituted 1-chloromethoxy-1-triazene 2-oxides with tetramethylammonium hydroxide results in corresponding [methylenebis(oxy)]bis(1-triazene 2-oxides). Treatment of 1-chloromethoxy-3-(2-hydroxyethyl)-3-methyl- 1-triazene 2-oxide with Me4NOH gives 16- and 24-membered intermolecular cyclization products.
Document Type:
Article
Language: English
Citation:
G. A. Smirnov, P. B. Gordeev, S. V. Nikitin, Yu. V. Nelyubina, G. V. Pokhvisneva, T. V. Ternikova, O. A. Luk'yanov, “Reaction of 3,3-disubstituted 1-chloromethoxy-1-triazene 2-oxides with tetramethylammonium hydroxide”, Mendeleev Commun., 27:6 (2017), 567–569
Linking options:
https://www.mathnet.ru/eng/mendc2061
https://www.mathnet.ru/eng/mendc/v27/i6/p567
This publication is cited in the following 7 articles:
P. B. Gordeev, G. A. Smirnov, “Synthesis of 1-(2-chloroethoxy-2-oxo)-3,3-dimethyltriaz-1-ene 2-oxide and some of its properties”, Russ Chem Bull, 74:1 (2025), 66
G. V. Pokhvisneva, S. D. Budina, G. A. Smirnov, “Reaction of arylsulfonyl chlorides with 1-methoxy-3-methyltriaz-1-ene 2-oxide sodium salt”, Russ Chem Bull, 73:5 (2024), 1328
P. B. Gordeev, G. A. Smirnov, “Alkylation of oxytriazene oxide salts with 2-(chloromethoxy)diazene 1-oxide derivatives”, Russ Chem Bull, 72:7 (2023), 1584
G. A. Smirnov, P. B. Gordeev, O. A. Luk'yanov, “Synthesis of 3,3-disubstituted 1-(1H-tetrazol-5-ylmethoxy)triaz-1-ene 2-oxides”, Russ Chem Bull, 69:1 (2020), 105
G. V. Pokhvisneva, P. B. Gordeev, S. V. Nikitin, G. A. Smirnov, T. V. Ternikova, O. A. Luk'yanov, “3,3-Bis(2-nitroxyethyl) derivatives of 1,1′-[methylenebis(oxy)]bis(triaz-1-ene 2-oxides) as a new type of NO donors”, Russ Chem Bull, 67:9 (2018), 1655
G. A. Smirnov, P. B. Gordeev, S. V. Nikitin, G. V. Pokhvisneva, T. V. Ternikova, I. M. Chistokhvalov, O. A. Luk'yanov, “Bis-, tris-, and tetrakis-N-(2-nitroxyethyl) derivatives of 1,1'-[methylenebis(oxy)]bis(triaz-1-ene 2-oxides)”, Russ Chem Bull, 67:9 (2018), 1662
S. G. Zlotin, A. M. Churakov, I. L. Dalinger, O. A. Luk'yanov, N. N. Makhova, A. Yu. Sukhorukov, V. A. Tartakovsky, “Recent advances in synthesis of organic nitrogen–oxygen systems for medicine and materials science”, Mendeleev Commun., 27:6 (2017), 535–546
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