Abstract:
Chemiluminescence was observed in ferrocene-catalyzed decomposition of bridged 1,2,4,5-tetraoxanes, namely, 2,3,5,6-tetraoxabicyclo[2.2.1]heptanes. The chemi- and photoluminescence spectra revealed the main products and luminescence emitters to be β-diketones. The reaction intermediate, the OOH radical, was found to catalyze the decomposition of the 1,2,4,5-tetraoxanes.
Document Type:
Article
Language: English
Citation:
D. I. Galimov, D. R. Gazeeva, R. G. Bulgakov, A. O. Terent'ev, “Chemiluminescence in decomposition of bridged 1,2,4,5-tetraoxanes catalyzed by ferrocene”, Mendeleev Commun., 27:4 (2017), 371–373
Linking options:
https://www.mathnet.ru/eng/mendc1998
https://www.mathnet.ru/eng/mendc/v27/i4/p371
This publication is cited in the following 1 articles:
Konstantin A. Tereshchenko, Daria A. Shiyan, Nikolai V. Ulitin, Sergei V. Kolesov, Sergey L. Khursan, “Experimental study and kinetic modeling of radical-coordination styrene polymerization with participation of ferrocene”, J Polym Res, 29:10 (2022)