P. V. Ivchenko, A. V. Shlyakhtin, I. E. Nifant'ev, “Ring-opening polymerization of glycolide and rac-lactide, catalyzed by aryloxy magnesium complexes: DFT study of reaction profile and stereocontrol mechanism”, Mendeleev Commun., 27:3 (2017), 278

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Mendeleev Communications, 2017, Volume 27, Issue 3, Pages 278–280
DOI: https://doi.org/10.1016/j.mencom.2017.05.020 (Mi mendc1967)

This article is cited in 16 scientific papers (total in 16 papers)

Communications

Ring-opening polymerization of glycolide and rac-lactide, catalyzed by aryloxy magnesium complexes: DFT study of reaction profile and stereocontrol mechanism

P. V. Ivchenko, A. V. Shlyakhtin, I. E. Nifant'ev

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Full-text PDF (422 kB) Citations (16)

DOI: https://doi.org/10.1016/j.mencom.2017.05.020

Graphic abstract: Ring-opening polymerization of glycolide and <i>rac</i>-lactide, catalyzed by aryloxy magnesium complexes: DFT study of reaction profile and stereocontrol mechanism

Abstract: DFT modeling shows that the most likely route of rac-lactide ring-opening polymerization, catalyzed by mono-aryloxy magnesium complexes, includes the formation of lower energy polymer-Mg chelates, which makes the formation of heterotactic polylactide preferable.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.2 Mb)

Citation: P. V. Ivchenko, A. V. Shlyakhtin, I. E. Nifant'ev, “Ring-opening polymerization of glycolide and rac-lactide, catalyzed by aryloxy magnesium complexes: DFT study of reaction profile and stereocontrol mechanism”, Mendeleev Commun., 27:3 (2017), 278–280

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This publication is cited in the following 16 articles:

Citing articles in Google Scholar: Russian citations, English citations
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