Abstract:
3,4,5-Triazidopyridine-2,6-dicarbonitrile, the first aromatic triazide with three adjacent azido groups in the ring, possessing the record positive heat of formation, was synthesized by azidation of 3,4,5-trichloropyridine-2,6-dicarbonitrile and characterized with X-ray analysis, thermogravimetry, differential scanning calorimetry and spectroscopic methods.
Citation:
S. V. Chapyshev, D. V. Korchagin, A. V. Chernyak, S. M. Aldoshin, “Synthesis and structure of 3,4,5-triazidopyridine-2,6-dicarbonitrile possessing the record positive heat of formation”, Mendeleev Commun., 27:2 (2017), 116–118
Linking options:
https://www.mathnet.ru/eng/mendc1914
https://www.mathnet.ru/eng/mendc/v27/i2/p116
This publication is cited in the following 3 articles:
Hui Zhang, Jinxiong Cai, Zhimin Li, Qi Lai, Ping Yin, Siping Pang, “Exploring a Fused Triazole–Tetrazine Binary CN Material for a Promising Initiating Substance”, ACS Appl. Mater. Interfaces, 16:4 (2024), 4628
D. B. Lempert, S. V. Chapyshev, A. I. Kazakov, N. A. Plishkin, A. V. Shikhovtsev, L. S. Yanovskii, “Thermochemical and energy characteristics di-, tri-, and tetraazide-substituted azines as gas-forming components of solid propellants for ramjet engines”, Combustion, Explosion and Shock Waves, 55:1 (2019), 23–31
S. V. Chapyshev, E. N. Ushakov, “Electron impact generation of tetraazidocyclobutadiene radical cation from tetraazidopyridine-2-carbonitrile”, Mendeleev Commun., 28:5 (2018), 470–471
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