Abstract:
One-pot functionalization of sp3 C–H bond in 1,1,1-trifluoro-2-(trifluoromethyl)decan-2-ol with CO and nucleophiles under the action of superelectrophilic complex CBr4·2 AlBr3 affords products of neo-structure and remote functionalities.
Citation:
I. S. Akhrem, D. V. Avetisyan, L. V. Afanas'eva, A. A. Tyutyunov, O. I. Artyushin, N. D. Kagramanov, “Regioselective functionalization of gem-bis(trifluoromethylated) alkanols”, Mendeleev Commun., 28:6 (2018), 651–652
Linking options:
https://www.mathnet.ru/eng/mendc1867
https://www.mathnet.ru/eng/mendc/v28/i6/p651
This publication is cited in the following 2 articles:
Mandeep Kaur Hunjan, Surabhi Panday, Anjali Gupta, Jayeeta Bhaumik, Parthasarathi Das, Joydev K. Laha, “Recent Advances in Functionalization of Pyrroles and their Translational Potential”, The Chemical Record, 21:4 (2021), 715
Douglas A. Klumpp, Maksim V. Anokhin, “Superelectrophiles: Recent Advances”, Molecules, 25:14 (2020), 3281