Abstract:
Random copolymers of ɛ-caprolactone with O-benzyl-protected 4-hydroxy- or 2,4-dihydroxy-δ-valerolactone after hydrogenation form γ-hydroxy functionalized polyesters that degrade via the cyclization to γ-butyrolactone fragments without carboxylic acid formation.
Citation:
I. E. Nifant'ev, A. V. Shlyakhtin, V. V. Bagrov, R. N. Ezhov, B. A. Lozhkin, A. V. Churakov, P. V. Ivchenko, “Ring-opened 4-hydroxy-δ-valerolactone subunit as a key structural fragment of polyesters that degrade without acid formation”, Mendeleev Commun., 28:6 (2018), 629–631
Linking options:
https://www.mathnet.ru/eng/mendc1859
https://www.mathnet.ru/eng/mendc/v28/i6/p629
This publication is cited in the following 5 articles:
M. A. Khavpachev, E. S. Trofimchuk, A. A. Puchkov, V. A. Demina, N. G. Sedush, N. I. Nikonorova, S. I. Balobanova, S. N. Chvalun, “Effect of ethanol solution of iodine on degradation of poly(ε-caprolactone)”, Mendeleev Commun., 33:3 (2023), 411–412
B. N. Mankaev, M. U. Agaeva, M. P. Egorov, S. S. Karlov, “Aluminum complexes based on 1,10-phenanthroline-containing diols: synthesis and application as initiators of polymerization of ε-caprolactone”, Russ Chem Bull, 71:4 (2022), 712
M. V. Zabalov, B. N. Mankaev, M. P. Egorov, S. S. Karlov, “DFT study of the role of substituents in tin(II) bis(amidoethyl)amine complexes used for ε-caprolactone polymerization”, Mendeleev Commun., 32:4 (2022), 460–463
E. A. Kuchuk, B. N. Mankaev, V. A. Serova, K. V. Zaitsev, A. V. Churakov, Yu. F. Oprunenko, G. S. Zaitseva, S. S. Karlov, “New dialkylenetriamine zinc complexes as highly efficient ROP catalysts”, Mendeleev Commun., 30:5 (2020), 596–598
B. N. Mankaev, K. V. Zaitsev, G. S. Zaitseva, A. V. Churakov, M. P. Egorov, S. S. Karlov, “Sterically hindered tetrylenes based on new 1,10-phenanthroline-containing diols: initiators for ε-caprolactone polymerization”, Russ Chem Bull, 68:2 (2019), 380
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