Abstract:
New olefin metathesis catalysts, unsaturated analogues of the Grubbs II and Hoveyda–Grubbs II ones, bearing bulky (alkoxy)hexafluoroisopropyl groups in one of the aryl substituent of NHC ligand provide high conversions in model ring closing metathesis of diallyl- and allylmethallylmalonates.
Citation:
T. R. Akmalov, S. M. Masoud, D. A. Petropavlovskikh, M. A. Zotova, S. E. Nefedov, S. N. Osipov, “New olefin metathesis catalysts with fluorinated unsymmetrical imidazole-based ligands”, Mendeleev Commun., 28:6 (2018), 609–611
Linking options:
https://www.mathnet.ru/eng/mendc1852
https://www.mathnet.ru/eng/mendc/v28/i6/p609
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S. M. Masoud, D. V. Vorobyeva, D. A. Petropavlovskikh, Christian Bruneau, S. N. Osipov, “Fluorine-containing ruthenium-based olefin metathesis catalysts”, Russian Chem. Reviews, 90:4 (2021), 419–450
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James W. Herndon, “The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2018”, Coordination Chemistry Reviews, 401 (2019), 213051
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