Abstract:
A matrix FTIR study of interaction between SiCl2 and 1,3-butadiene revealed that at low temperatures, it stops at the step of complexation between the reactants. This allowed us to investigate a photochemical version of this interaction resulting in the formation of both 1,1-dichloro-1-silacyclopent-3-ene and 1,1-dichloro-2-vinylsilirane in contrast to the thermal reaction giving only the first of these products.
Citation:
S. E. Boganov, V. M. Promyslov, S. S. Rynin, I. V. Krylova, M. P. Egorov, “Formation of 1,1-dichloro-2-vinyl-1-silacyclopropane by a photoinduced reaction between dichlorosilylene and 1,3-butadiene”, Mendeleev Commun., 28:6 (2018), 574–576
Linking options:
https://www.mathnet.ru/eng/mendc1839
https://www.mathnet.ru/eng/mendc/v28/i6/p574
This publication is cited in the following 6 articles:
M. P. Egorov, V. P. Ananikov, E. G. Baskir, S. E. Boganov, V. I. Bogdan, A. N. Vereshchagin, V. A. Vil', I. L. Dalinger, A. D. Dilman, O. L. Eliseev, S. G. Zlotin, E. A. Knyazeva, V. M. Kogan, L. O. Kononov, M. M. Krayushkin, V. B. Krylov, L. M. Kustov, V. V. Levin, B. V. Lichitsky, M. G. Medvedev, N. E. Nifantiev, O. A. Rakitin, A. M. Sakharov, I. V. Svitanko, G. A. Smirnov, A. Yu. Stakheev, M. A. Syroeshkin, A. O. Terent'ev, Yu. V. Tomilov, E. V. Tretyakov, I. V. Trushkov, L. L. Fershtat, V. A. Chaliy, V. Z. Shirinian, “Current trends in organic chemistry: contribution of the N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences”, Russ Chem Bull, 73:9 (2024), 2423
Yunus E. Türkmen, Comprehensive Heterocyclic Chemistry IV, 2022, 506
Sergey E. Boganov, Rosa Becerra, Vladimir M. Promyslov, Pavel G. Shangin, Andrey V. Lalov, Mikhail P. Egorov, Robin Walsh, “Photoinduced reaction of dichlorosilylene with acetylene: Matrix isolation FTIR spectroscopic study”, Journal of Organometallic Chemistry, 962 (2022), 122270
S. E. Boganov, V. M. Promyslov, A. V. Lalov, M. A. Syroeshkin, M. P. Egorov, “Nonclassical complex of dichlorosilylene with CO: direct spectroscopic detection”, Russ Chem Bull, 70:6 (2021), 1084
Yu. V. Tomilov, L. G. Menchikov, E. A. Shapiro, V. D. Gvozdev, K. N. Shavrin, N. V. Volchkov, M. B. Lipkind, M. P. Egorov, S. E. Boganov, V. N. Khabashesku, E. G. Baskir, “Carbenes, related intermediates, and small-sized cycles: contribution from Professor Nefedov's laboratory”, Mendeleev Commun., 31:6 (2021), 750–768
S. E. Boganov, V. M. Promyslov, P. G. Shangin, M. A. Syroeshkin, M. P. Egorov, “Interaction of SiCl2 with CO2 in Ar matrices”, Mendeleev Commun., 31:2 (2021), 149–153
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