Abstract:
Reaction of a trinuclear silver pyrazolate {[3,5-(CF3)2Pz]Ag}3 complex with tricyclohexylphosphine at different reagent ratios leads to the formation of heteroleptic dinuclear or tetranuclear complexes. According to the single crystal X-ray analysis of the dinuclear complex, hexane molecules are incorporated into the cavities formed as the result of supramolecular packing. Coordination of a phosphine ligand makes dinuclear silver pyrazolate to exhibit blue emission at room temperature.
Citation:
A. A. Titov, A. F. Smol'yakov, K. F. Baranova, O. A. Filippov, E. S. Shubina, “Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis(trifluoromethyl)pyrazolates”, Mendeleev Commun., 28:4 (2018), 387–389
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https://www.mathnet.ru/eng/mendc1775
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