Abstract:
A new highly efficient solvent-free method for aryl bromide (iodide) homocoupling comprising the use of Pd(OAc)2/PCy3 system in the presence of CsF is suitable for substrates bearing functional groups not tolerant to lithium-, magnesium-, zincorganic reagents and strong bases.
Document Type:
Article
Language: English
Citation:
P. S. Gribanov, Yu. D. Golenko, M. A. Topchiy, A. N. Philippova, N. Yu. Kirilenko, N. V. Krivoshchapov, G. K. Sterligov, A. F. Asachenko, M. V. Bermeshev, M. S. Nechaev, “One-pot two-step stannylation/Stille homocoupling of aryl bromides and iodides under solvent-free conditions”, Mendeleev Commun., 28:3 (2018), 323–325
Linking options:
https://www.mathnet.ru/eng/mendc1753
https://www.mathnet.ru/eng/mendc/v28/i3/p323
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M. A. Topchiy, A. N. Lysenko, M. A. Rasskazova, A. A. Ageshina, S. A. Rzhevskiy, L. I. Minaeva, M. S. Nechaev, A. F. Asachenko, “Arylation of nitromethane with sterically hindered aryl halides”, Russ Chem Bull, 71:1 (2022), 59
Pavel S. Gribanov, Edita M. Atoian, Anna N. Philippova, Maxim A. Topchiy, Andrey F. Asachenko, Sergey N. Osipov, “One‐Pot Synthesis of 5‐Amino‐1,2,3‐triazole Derivatives via Dipolar Azide-Nitrile Cycloaddition and Dimroth Rearrangement under Solvent‐Free Conditions”, Eur J Org Chem, 2021:9 (2021), 1378
Sergey A. Rzhevskiy, Maxim A. Topchiy, Vasilii N. Bogachev, Lidiya I. Minaeva, Ilia R. Cherkashchenko, Konstantin V. Lavrov, Grigorii K. Sterligov, Mikhail S. Nechaev, Andrey F. Asachenko, “Solvent-free palladium-catalyzed C–O cross-coupling of aryl bromides with phenols”, Mendeleev Communications, 31:3 (2021), 409
S. A. Rzhevskiy, V. N. Bogachev, L. I. Minaeva, G. K. Sterligov, M. S. Nechaev, M. A. Topchiy, A. F. Asachenko, “Efficient synthesis of 3-arylbutadiene sulfones using the Heck–Matsuda reaction”, Mendeleev Commun., 31:4 (2021), 548–549
G. A. Chesnokov, A. A. Ageshina, A. V. Maryanova, S. A. Rzhevskiy, P. S. Gribanov, M. A. Topchiy, M. S. Nechaev, A. F. Asachenko, “Nitromethane as a reagent for the synthesis of 3-nitroindoles from 2-haloarylamine derivatives”, Russ Chem Bull, 69:12 (2020), 2370
P. S. Gribanov, G. A. Chesnokov, P. B. Dzhevakov, N. Yu. Kirilenko, S. A. Rzhevskiy, A. A. Ageshina, M. A. Topchiy, M. V. Bermeshev, A. F. Asachenko, M. S. Nechaev, “Solvent-free Suzuki and Stille cross-coupling reactions of 4- and 5-halo-1,2,3-triazoles”, Mendeleev Commun., 29:2 (2019), 147–149
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