Abstract:
Rhodium-catalysed hydroformylation of styrene and aliphatic olefins under biphasic conditions in the presence of watersoluble 1,4,7-triaza-9-phosphatricyclo[5.3.2.14,9]tridecane (CAP) chemoselectively affords aldehydes. Multiple catalyst reuse without loss in performance is demonstrated.
Document Type:
Article
Language: English
Citation:
O. L. Eliseev, T. N. Bondarenko, S. N. Britvin, P. P. Khodorchenko, A. L. Lapidus, “Efficient water-soluble catalytic system RhI-CAP for biphasic hydroformylation of olefins”, Mendeleev Commun., 28:3 (2018), 264–266
Linking options:
https://www.mathnet.ru/eng/mendc1732
https://www.mathnet.ru/eng/mendc/v28/i3/p264
This publication is cited in the following 6 articles:
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Antonella Guerriero, Maurizio Peruzzini, Luca Gonsalvi, “Synthesis of New Ruthenium‐CAP Complexes and Use as Catalysts for Benzonitrile Hydration to Benzamide”, Eur J Inorg Chem, 2021:45 (2021), 4669
W. Alsalahi, A.M. Trzeciak, “Rhodium-catalyzed hydroformylation under green conditions: Aqueous/organic biphasic, “on water”, solventless and Rh nanoparticle based systems”, Coordination Chemistry Reviews, 430 (2021), 213732
Antonella Guerriero, Luca Gonsalvi, “From traditional PTA to novel CAP: A comparison between two adamantane cage-type aminophosphines”, Inorganica Chimica Acta, 518 (2021), 120251
Shepherd Siangwata, Neill J. Goosen, Gregory S. Smith, “Aqueous olefin hydroformylation using water-soluble mono- and trinuclear N,O-chelate rhodium(I)-aryl ether precatalysts”, Applied Catalysis A: General, 603 (2020), 117736
Alexander E. Miroslavov, Sergey N. Britvin, Henrik Braband, Roger Alberto, Ekaterina S. Stepanova, Anna P. Shevyakova, Georgy V. Sidorenko, Alexander A. Lumpov, “Water-soluble carbonyl complexes of 99Tc(I) and Re(I) with adamantane-cage aminophosphines PTA and CAP”, Journal of Organometallic Chemistry, 896 (2019), 83