E. E. Kim, D. S. Ionov, A. D. Volodin, A. A. Korlyukov, Yu. N. Kononevich, V. K. Brel, “Synthesis and luminescent properties of a new manganese complex based on N-substituted bis(diphenylphosphoryl)pyrrolidine”, Mendeleev Commun., 35:1 (2025), 42

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Mendeleev Communications, 2025, Volume 35, Issue 1, Pages 42–44
DOI: https://doi.org/10.71267/mencom.7577 (Mi mendc17)

Communications

Synthesis and luminescent properties of a new manganese complex based on N-substituted bis(diphenylphosphoryl)pyrrolidine

E. E. Kim^a, D. S. Ionov^b, A. D. Volodin^a, A. A. Korlyukov^ac, Yu. N. Kononevich^a, V. K. Brel^a

^a A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119334 Moscow, Russian Federation
^b Photochemistry Center, Kurchatov Complex of Crystallography and Photonics, National Research Center 'Kurchatov Institute', 119421 Moscow, Russian Federation
^c N. I. Pirogov Russian National Research Medical University, 117997 Moscow, Russian Federation

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DOI: https://doi.org/10.71267/mencom.7577

Graphic abstract: Synthesis and luminescent properties of a new manganese complex based on <em>N</em>-substituted bis(diphenylphosphoryl)pyrrolidine

Abstract: A new luminescent Mn^II complex based on 1-benzyl-3,4-bis(diphenylphosphoryl)pyrrolidine ligand has been synthesized and fully characterized. This complex exhibits intense luminescence in the solid state (λ_em = 585 nm) with a high quantum yield (60%) as well as luminescence lifetime of 17 ms.

Keywords: luminescence, X-ray diffraction analysis, manganese(II) complexes, phosphorus-containing ligands, NMR spectroscopy.

Funding agency	Grant number
Russian Science Foundation	20-13-00329
Ministry of Science and Higher Education of the Russian Federation	075-00277-24-00

Received: 23.07.2024
Accepted: 16.09.2024

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.3 Mb)

Citation: E. E. Kim, D. S. Ionov, A. D. Volodin, A. A. Korlyukov, Yu. N. Kononevich, V. K. Brel, “Synthesis and luminescent properties of a new manganese complex based on N-substituted bis(diphenylphosphoryl)pyrrolidine”, Mendeleev Commun., 35:1 (2025), 42–44

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