Abstract:
Resorcinol–formaldehyde aerogels obtained in methyl trifluoropyruvate (MTFP) possess a fluorinated matrix due to the mechanism of electrophilic substitution in the resorcinol moiety with the formation of C–C bond. The use of MTFP as a solvent also substantially accelerates the formaldehyde– resorcinol interaction.
Document Type:
Article
Language: English
Citation:
S. A. Lermontov, A. N. Malkova, N. A. Sipyagina, A. V. Semakov, A. Y. Baranchikov, V. K. Ivanov, “Methyl trifluoropyruvate – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels”, Mendeleev Commun., 28:1 (2018), 102–104
Linking options:
https://www.mathnet.ru/eng/mendc1679
https://www.mathnet.ru/eng/mendc/v28/i1/p102
This publication is cited in the following 4 articles:
Tomaž Skapin, Springer Handbooks, Springer Handbook of Aerogels, 2023, 1011
Kh. E. Yorov, A. E. Baranchikov, M. A. Kiskin, A. A. Sidorov, V. K. Ivanov, “Functionalization of Aerogels with Coordination Compounds”, Russ J Coord Chem, 48:2 (2022), 89
S. A. Lermontov, A. E. Baranchikov, N. A. Sipyagina, A. N. Malkova, G. P. Kopitsa, Kh. E. Yorov, O. S. Ivanova, A. Len, V. K. Ivanov, “Is Supercritical So Critical? The Choice of Temperature to Synthesize SiO2 Aerogels”, Russ. J. Inorg. Chem., 65:2 (2020), 255
Mina Noroozi, Mahyar Panahi-Sarmad, Mahbod Abrisham, Arian Amirkiai, Narges Asghari, Hooman Golbaten-Mofrad, Navid Karimpour-Motlagh, Vahabodin Goodarzi, Ahmad Reza Bahramian, Beniamin Zahiri, “Nanostructure of Aerogels and Their Applications in Thermal Energy Insulation”, ACS Appl. Energy Mater., 2:8 (2019), 5319