Abstract:
Silatranes bearing an amide group in the axial chain have been synthesized by the reaction of 1-(3-aminopropyl)silatrane with arylchalcogenylacetic acids (Het)ArYCH2CO2H [(Het)Ar=2-MeC6H4, 4-Cl-2-MeC6H3, 4-ClC6H4, 3-indolyl; Y=O, S], and their structures have been established by 1H,13C, 15N, 29Si NMR and IR spectroscopy. When 4-chlorophenylsulfonylacetic acid was employed, the reaction proceeded unexpectedly via the 4-chlorophenyl methyl sulfone intermediate and resulted in methyl 4-[3-(1 silatranyl)propylamino]phenyl sulfone.
Citation:
S. N. Adamovich, E. N. Oborina, I. A. Ushakov, “Amide derivatives of 3-aminopropylsilatrane”, Mendeleev Commun., 29:6 (2019), 688–689
Linking options:
https://www.mathnet.ru/eng/mendc1632
https://www.mathnet.ru/eng/mendc/v29/i6/p688
This publication is cited in the following 5 articles:
Irina V. Sterkhova, Alexander A. Korlyukov, Natalya F. Lazareva, Vladimir I. Smirnov, “Silatranes: Relationship between the experimental Si ← N dative bond length and its calculated energy according to AIM analysis data”, Chemical Physics, 578 (2024), 112153
S. N. Adamovich, I. A. Ushakov, A. V. Afonin, N. V. Vchislo, E. N. Oborina, D. V. Pavlov, “O- and S-containing 1-azadiene derivatives of 3-aminopropylsilatrane”, Russ Chem Bull, 70:2 (2021), 406
S. N. Adamovich, E. Kh. Sadykov, I. A. Ushakov, E. N. Oborina, L. A. Belovezhets, “Antibacterial activity of new silatrane pyrrole-2-carboxamide hybrids”, Mendeleev Commun., 31:2 (2021), 204–206
Olga Glyzina, Sergey Adamovich, Olga Belykh, Lyubov Sukhanova, Elizaveta Oborina, Leonid Glyzin, Vera Yakhnenko, Marina Tyagun, Yulia Sapozhnikova, “Prospects of the Use of Synthetic Biostimulants for the Development of Aquaculture of Whitefishes in Lake Baikal”, Bulletin of Baikal State University, 30:3 (2020), 463
Yu. A. Kondratenko, V. L. Ugolkov, D. Yu. Vlasov, T. A. Kochina, “Synthesis and characterization of triethanolamine complexes with cobalt(ii) and zinc(ii) cinnamates”, Mendeleev Commun., 30:5 (2020), 639–641
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