Abstract:
α-Diphenylphosphino-N-(pyrazin-2-yl)glycine was synthesized by the three-component condensation of diphenylphosphine, glyoxylic acid hydrate, and 2-aminopyrazine and its structure was confirmed by X-ray diffraction. It reacted with [Ni(COD)2] (COD is cycloocta-1,5-diene) to give complexes that were tested as catalysts for selective dimerization/oligomerization of ethylene to but-1-ene (main product) and C6–C14 α-olefins, respectively.
Citation:
O. S. Soficheva, G. E. Bekmukhamedov, A. B. Dobrynin, J. W. Heinicke, O. G. Sinyashin, D. G. Yakhvarov, “α-Diphenylphosphino-N-(pyrazin-2-yl)glycine as a ligand in Ni-catalyzed ethylene oligomerization”, Mendeleev Commun., 29:5 (2019), 575–577
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https://www.mathnet.ru/eng/mendc/v29/i5/p575
This publication is cited in the following 12 articles:
O. S. Soficheva, G. E. Bekmukhamedov, D. G. Yakhvarov, “Catalytic Synthesis of Butene-1 and Hexene-1 in the Homogeneous Oligomerization of Ethylene in the Presence of Nickel Complexes Based on N-Heteroaryl-Substituted α-Diphenylphosphinoglycines”, Kinet Catal, 65:1 (2024), 8
O. S. Soficheva, G. E. Bekmukhamedov, D. G. Yakhvarov, “Catalytic Synthesis of Butene-1 and Hexene-1 in the Homogeneous Oligomerization of Ethylene in the Presence of Nickel Complexes Based on N-Heteroaryl-Substituted α-Diphenylphosphinoglycines”, Kinetika i kataliz, 65:1 (2024), 12
Lukáš Hanzl, Jaromír Vinklárek, Libor Dostál, Ivana Císařová, Miroslava Litecká, Jan Honzíček, “Stabilization of propene molybdenum and tungsten half–sandwich complexes by intramolecular coordination of a thioether function”, RSC Adv., 13:29 (2023), 19746
Dmitry V. Moiseev, Brian R. James, “Phospha-Mannich reactions of RPH2, R2PH, and R3P”, Phosphorus, Sulfur, and Silicon and the Related Elements, 197:4 (2022), 327
Na Zhang, Yansong Wu, Yuying Li, Liduo Chen, Mingshui Zhang, Jun Wang, “Star iminopyridyl iron, cobalt and nickel complexes: synthesis, molecular structures, and evaluation as ethylene oligomerization catalysts”, Polym. Bull., 79:6 (2022), 4219
Alina A. Kagileva, Alexey A. Kagilev, Artyom O. Kantyukov, Zufar N. Gafurov, Il'yas F. Sakhapov, Giyjaz E. Bekmukhamedov, Khasan R. Khayarov, Ekaterina M. Zueva, Olga S. Soficheva, Dmitry G. Yakhvarov, “Influence of N- and P-substituents in N-aryl-phosphinoglycine ligands on the selectivity of Ni-catalysed ethylene oligomerization”, New J. Chem., 46:36 (2022), 17303
Shah Imtiaz, Jahangir Ahmad war, Syqa Banoo, Sarfaraz khan, “α-Aminoazoles/azines: key reaction partners for multicomponent reactions”, RSC Adv., 11:19 (2021), 11083
K. N. Gavrilov, I. V. Chuchelkin, V. K. Gavrilov, S. V. Zheglov, I. D. Firsin, V. M. Trunina, A. V. Maximychev, A. M. Perepukhov, “Pd-Catalyzed asymmetric allylation involving bis(diamidophosphite) based on the salen-type chiral diamine”, Russ Chem Bull, 70:2 (2021), 336
Giyjaz E. Bekmukhamedov, Aleksandr V. Sukhov, Aidar M. Kuchkaev, Dmitry G. Yakhvarov, “Ni-Based Complexes in Selective Ethylene Oligomerization Processes”, Catalysts, 10:5 (2020), 498
M. I. Rogovoy, M. P. Davydova, I. Yu. Bagryanskaya, A. V. Artem'ev, “Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its AgI, AuI and PtII complexes”, Mendeleev Commun., 30:3 (2020), 305–307
Yu. Yu. Titova, T. V. Kon'kova, B. G. Sukhov, F. K. Schmidt, “Nickel-containing nanophases as the carriers of catalytic active sites in the ethylene oligomerization in the presence of systems based on Ni(acac)2 and organoaluminum compounds”, Mendeleev Commun., 30:4 (2020), 465–467
O. S. Soficheva, A. A. Nesterova, A. B. Dobrynin, E. M. Zueva, J. W. Heinicke, O. G. Sinyashin, D. G. Yakhvarov, “The effect of N-substituent on the relative thermodynamic stability of unionized and zwitterionic forms of α-diphenylphosphino-α-amino acids”, Mendeleev Commun., 30:4 (2020), 516–518
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