Abstract:
Reactions of nickel(iv) bis(dicarbollide) with 2,2′-bipyridine or 1,10-phenanthroline in ethanol result in destruction of the metallacarborane cage with formation of the parent and 3-ethoxy substituted nido-carboranes.
Citation:
E. P. Andreichuk, A. A. Anisimov, A. V. Shmalko, K. Yu. Suponitsky, I. B. Sivaev, V. I. Bregadze, “Stability of nickel bis(dicarbollide) complexes”, Mendeleev Commun., 29:5 (2019), 534–536
Linking options:
https://www.mathnet.ru/eng/mendc1582
https://www.mathnet.ru/eng/mendc/v29/i5/p534
This publication is cited in the following 8 articles:
Igor B. Sivaev, “Bis(Dicarbollide) Complexes of Transition Metals: How Substituents in Dicarbollide Ligands Affect the Geometry and Properties of the Complexes”, Molecules, 29:15 (2024), 3510
Dmitriy K. Semyonov, Georgii K. Slushko, Marina Yu. Stogniy, Sergey A. Anufriev, Ivan A. Godovikov, Kyrill Yu. Suponitsky, Vladimir I. Bregadze, Igor B. Sivaev, “Interligand Interactions in Half-Sandwich Nickelacarboranes with Phosphine Ligands: Away from Skeletal Rearrangements”, Organometallics, 42:18 (2023), 2522
Lukáš Fojt, Bohumír Grüner, Josef Holub, Luděk Havran, Miroslav Fojta, “Electrochemistry of icosahedral metal full and half sandwich metallacarboranes in phosphate buffers”, Journal of Electroanalytical Chemistry, 910 (2022), 116165
Vitalii E. Konoplev, Fedor M. Dolgushin, Dmitry A. Loginov, Maxim V. Tachaev, “Step-by-step polyhedral contraction of the osmacarborane framework {OsCB10} → {OsCB9} → {OsCB8}”, Journal of Organometallic Chemistry, 949 (2021), 121948
Varvara V. Avdeeva, Elena A. Malinina, Anna V. Vologzhanina, Igor B. Sivaev, Nikolay T. Kuznetsov, “Formation of oxidopolyborates in destruction of the [B11H14]– anion promoted by transition metals”, Inorganica Chimica Acta, 509 (2020), 119693
Ekaterina P. Andreichuk, Sergey A. Anufriev, Kyrill Yu. Suponitsky, Igor B. Sivaev, “The First Nickelacarborane with closo-nido Structure”, Molecules, 25:24 (2020), 6009
Sergey A. Anufriev, Akim V. Shmal'ko, Marina Yu. Stogniy, Kyrill Yu. Suponitsky, Igor B. Sivaev, “Isomeric ammonio derivatives of nido-carborane 3- and 10-H3N-7,8-C2B9H11”, Phosphorus, Sulfur, and Silicon and the Related Elements, 195:11 (2020), 901
Sergey A. Anufriev, Kyrill Yu. Suponitsky, Oleg A. Filippov, Igor B. Sivaev, “Synthesis and Structure of Methylsulfanyl Derivatives of Nickel Bis(Dicarbollide)”, Molecules, 24:24 (2019), 4449
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