Abstract:
2,3-Dihydroxypropyl functionalized polyphosphates obtained via controlled acid-catalyzed hydrolysis of 2-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]- or 2-(oxiran-2-ylmethoxy)-1,3,2-dioxaphospholane 2-oxide homopolymers are highly sensitive to basic hydrolysis along the polyphosphate chain.
Citation:
M. A. Kosarev, D. E. Gavrilov, I. E. Nifant'ev, A. V. Shlyakhtin, A. N. Tavtorkin, V. P. Dyadchenko, V. A. Roznyatovsky, P. V. Ivchenko, “Ultrafast hydrolytic degradation of 2,3-dihydroxypropyl functionalized poly(ethylene phosphates)”, Mendeleev Commun., 29:5 (2019), 509–511
Linking options:
https://www.mathnet.ru/eng/mendc1573
https://www.mathnet.ru/eng/mendc/v29/i5/p509
This publication is cited in the following 7 articles:
E. R. Nurieva, Yu. G. Borisova, G. Z. Raskildina, R. M. Sultanova, S. S. Zlotsky, “Synthesis, Reactions and Application of 2,2-Dimethyl-4-oxymethyl-1,3-dioxolane (A Review)”, Žurnal obŝej himii, 94:6 (2024), 664
Timo Rheinberger, Oscar Rabaux, Christine Jérôme, Frederik R. Wurm, “The future of polyphosphoesters”, European Polymer Journal, 200 (2023), 112464
Timo Rheinberger, Mareike Deuker, Frederik R. Wurm, “The microstructure of polyphosphoesters controls polymer hydrolysis kinetics from minutes to years”, European Polymer Journal, 190 (2023), 111999
Ilya E. Nifant'ev, Andrey V. Shlyakhtin, Vladimir V. Bagrov, Alexander N. Tavtorkin, Sergey O. Ilyin, Dmitry E. Gavrilov, Pavel V. Ivchenko, “Cyclic ethylene phosphates with (CH2)nCOOR and CH2CONMe2 substituents: synthesis and mechanistic insights of diverse reactivity in aryloxy-Mg complex-catalyzed (co)polymerization”, Polym. Chem., 12:47 (2021), 6937
Soumabrata Majumdar, Brahim Mezari, Huiyi Zhang, Jeroen van Aart, Rolf A. T. M. van Benthem, Johan P. A. Heuts, Rint P. Sijbesma, “Efficient Exchange in a Bioinspired Dynamic Covalent Polymer Network via a Cyclic Phosphate Triester Intermediate”, Macromolecules, 54:17 (2021), 7955
Ilya Nifant'ev, Andrey Shlyakhtin, Pavel Komarov, Alexander Tavtorkin, Evgeniya Kananykhina, Andrey Elchaninov, Polina Vishnyakova, Timur Fatkhudinov, Pavel Ivchenko, “In Vitro and In Vivo Studies of Biodegradability and Biocompatibility of Poly(εCL)-b-Poly(EtOEP)-Based Films”, Polymers, 12:12 (2020), 3039
Chiara Pelosi, Maria R. Tinè, Frederik R. Wurm, “Main-chain water-soluble polyphosphoesters: Multi-functional polymers as degradable PEG-alternatives for biomedical applications”, European Polymer Journal, 141 (2020), 110079
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