Abstract:
Calculations by the hybrid functional PBE0 with scalar relativistic corrections and the QTAIM method revealed the metal-metal bonding in the molecule of platinum(II) acetate Pt4(μ-OAc)8, which stabilizes the molecule by 50kcalmol−1.
Citation:
A. A. Markov, I. A. Yakushev, A. V. Churakov, V. N. Khrustalev, N. V. Cherkashina, I. P. Stolarov, A. E. Gekhman, M. N. Vargaftik, “Structure and quantum chemical study of crystalline platinum(II) acetate”, Mendeleev Commun., 29:5 (2019), 489–491
Linking options:
https://www.mathnet.ru/eng/mendc1566
https://www.mathnet.ru/eng/mendc/v29/i5/p489
This publication is cited in the following 6 articles:
M. V. Panina, N. K. Ogarkova, P. V. Dorovatovskii, O. V. Sulimova, E. A. Sosunov, N. V. Cherkashina, J. E. Makarevich, M. A. Navasardyan, A. S. Popova, I. A. Yakushev, “Highly efficient synthesis of mononuclear Pt-based carboxylic complexes trans-[Py2Pt(OC(O)R)2] (R = Me, But, Ph)”, Mendeleev Commun., 34:6 (2024), 808–811
I. A. Yakushev, M. Yu. Nesterenko, P. V. Dorovatovskii, A. B. Kornev, A. D. Maksimova, A. S. Popova, N. V. Cherkashina, A. V. Churakov, M. N. Vargaftik, “Tetrapyridineplatinum(II) Carboxylates: Synthesis and Crystal Structure”, Koordinacionnaâ himiâ, 49:1 (2023), 51
I. A. Yakushev, M. Yu. Nesterenko, P. V. Dorovatovskii, A. B. Kornev, A. D. Maksimova, A. S. Popova, N. V. Cherkashina, A. V. Churakov, M. N. Vargaftik, “Tetrapyridineplatinum(II) Carboxylates: Synthesis and Crystal Structure”, Russ J Coord Chem, 48:12 (2022), 935
Maria G. Khrenova, Anastasia Yu. Soloveva, Larisa A. Varfolomeeva, Tamara V. Tikhonova, Vladimir O. Popov, “The O to S substitution in urea brings inhibition activity against thiocyanate dehydrogenase”, Mendeleev Communications, 31:3 (2021), 373
Ilya A. Yakushev, Igor P. Stolarov, Natalia V. Cherkashina, Andrei V. Churakov, Yan V. Zubavichus, Alexander A. Markov, Alexander E. Gekhman, Michael N. Vargaftik, “Two routes to platinum-based carboxylate-bridged heterometallics”, Inorganica Chimica Acta, 508 (2020), 119631
I. P. Stolarov, N. V. Cherkashina, I. A. Yakushev, A. V. Churakov, A. B. Kornev, E. V. Fatyushina, “New Heterometallic Carboxylate Complexes of Platinum and Iron, Precursors for Nanosized Intermetallic Compound PtFe Production”, Russ. J. Inorg. Chem., 65:4 (2020), 507
Contact us: