Abstract:
The oxidative dehydrogenation of ethane in the supercritical state into ethylene on MoVNbTeOx oxide catalysts at the total pressure of an O2-containing mixture of 100 atm was carried out. The high reaction pressure allowed us to decrease the temperature from 360∘C at 1 atm to 280∘C at 100 atm along with the increased productivity of C2H4 from
205 to 290gC2H4h−1kg−1cat, respectively. Moreover, the higher pressure also prevents the destruction of M1 phase of the catalyst via the reduction of Te.
Document Type:
Article
Language: English
Citation:
I. I. Mishanin, V. I. Bogdan, “Advantages of ethane oxidative dehydrogenation on the MoVNbTeOx catalyst under elevated pressure”, Mendeleev Commun., 29:4 (2019), 455–457
\Bibitem{MisBog19}
\by I.~I.~Mishanin, V.~I.~Bogdan
\paper Advantages of ethane oxidative dehydrogenation on the $\mathrm{MoVNbTeO_x}$ catalyst under elevated pressure
\jour Mendeleev Commun.
\yr 2019
\vol 29
\issue 4
\pages 455--457
\mathnet{http://mi.mathnet.ru/mendc1557}
\crossref{https://doi.org/10.1016/j.mencom.2019.07.034}
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https://www.mathnet.ru/eng/mendc/v29/i4/p455
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