Abstract:
New m-carborane-containing siloxanes were obtained by the Grignard reaction based on chloromethyl-m-carboranes and chlorodimethylsiloxanes. In case of (7-methyl-m-carboran-1-yl)methyl chloride, side processes of isomerization and transmetalation do not occur, which provides the yield of the desired product as high as 87%.
Document Type:
Article
Language: English
Citation:
B. A. Izmaylov, V. A. Vasnev, G. D. Markova, “New preparative Grignard synthesis of (m-carboranylmethyl)siloxanes from chlorodimethylsiloxanes”, Mendeleev Commun., 29:2 (2019), 194–195
Linking options:
https://www.mathnet.ru/eng/mendc1468
https://www.mathnet.ru/eng/mendc/v29/i2/p194
This publication is cited in the following 3 articles:
V. A. Vasnev, G. D. Markova, “Recent Advances in the Field of Polycarboranesiloxanes Synthesis”, Polym. Sci. Ser. C, 64:2 (2022), 176
B. A. Izmaylov, V. A. Vasnev, G. D. Markova, “Novel oligo-m-carboranylenemethylenesilanes”, Russ Chem Bull, 69:6 (2020), 1130
Ekaterina O. Minyaylo, Anton A. Anisimov, Andrei V. Zaitsev, Valentina A. Ol'shevskaya, Alexander S. Peregudov, Elena G. Kononova, Olga I. Shchegolikhina, Aziz M. Muzafarov, Martin Möller, “Synthesis of new carboranyl organosilicon derivatives – precursors for the preparation of hybrid organo-inorganic materials”, Journal of Organometallic Chemistry, 928 (2020), 121547
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