Abstract:
1,7-Dihydrodiimidazo[4,5-b:4′,5′-e]pyridine obtained by reductive heterocyclization was N-arylated with 4-fluoronitrobenzene to form two regioisomers in 7 : 3 ratio. This N-arylation is considered as a model reaction for the polymer synthesis.
Citation:
D. Yu. Razorenov, S. A. Makulova, I. V. Fedyanin, K. A. Lyssenko, K. M. Skupov, Yu. A. Volkova, I. I. Ponomarev, I. I. Ponomarev, “Diimidazo[4,5-b:4′,5′-e]pyridine: synthesis and nucleophilic aromatic substitution reaction”, Mendeleev Commun., 29:2 (2019), 181–183
Linking options:
https://www.mathnet.ru/eng/mendc1464
https://www.mathnet.ru/eng/mendc/v29/i2/p181
This publication is cited in the following 3 articles:
Alexey M. Starosotnikov, Maxim A. Bastrakov, “Dinitropyridines: Synthesis and Reactions”, Asian J Org Chem, 2024
M. R. Crampton, Organic Reaction Mechanisms Series, Organic Reaction Mechanisms 2019, 2023, 179
I. I. Ponomarev, D. Yu. Razorenov, V. A. Muravyova, K. M. Skupov, Yu. A. Volkova, Iv. I. Ponomarev, M. M. Ilyin, E. M. Chaika, “New Polymers Containing N-Phenylenebenzimidazole and N-Phenylene-Diimidazopyridine Units for Fuel Cell Proton-Conducting Membranes”, Polym. Sci. Ser. C, 62:2 (2020), 214
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