Abstract:
A new complex of nickel acrylate and 4’-phenyl-2,2’:6’,2’’- terpyridine, analogs of which have been previously used to obtain self-healing metallopolymers, has been prepared. The complex was analyzed by X-ray diffraction, IR and UV absorption spectroscopy, differential scanning calorimetry and thermogravimetric analysis. The values of effective activation energy of solid-phase polymerization and heat of double bond opening for this complex have been calculated.
Citation:
E. S. Sorin, R. K. Baimuratova, V. V. Tkachev, A. N. Utenyshev, A. V. Kuzmin, G. I. Dzhardimalieva, “Structure and properties of the metal-containing monomer based on nickel acrylate and 4'-phenyl-2,2':6',2''-terpyridine for self-healing polymers”, Mendeleev Commun., 34:3 (2024), 382–384
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https://www.mathnet.ru/eng/mendc135
https://www.mathnet.ru/eng/mendc/v34/i3/p382
This publication is cited in the following 3 articles:
E. N. Shepelenko, V. A. Podshibyakin, O. P. Demidov, K. E. Shepelenko, V. M. Chernyshev, Mendeleev Commun., 35:1 (2025), 96–98
Rose K. Baimuratova, Evgeny S. Sorin, Denis V. Korchagin, Lavrenty G. Gutsev, Gennadii V. Shilov, Vladimir A. Zhinzhilo, Igor E. Uflyand, Alexander V. Akkuratov, Gulzhian I. Dzhardimalieva, “Crystal structure, thermal and luminescent properties of the complex of zinc(II) acrylate and 4′-phenyl-2,2′:6′,2″-terpyridine”, Inorganica Chimica Acta, 581 (2025), 122649
Evgeny S. Sorin, Rose K. Baimuratova, Mikhail V. Zhidkov, Maria L. Bubnova, Evgeniya O. Perepelitsina, Ainur F. Abukaev, Denis V. Anokhin, Dmitry A. Ivanov, Gulzhian I. Dzhardimalieva, “High-Strength, Self-Healing Copolymers of Acrylamide and Acrylic Acid with Co(II), Ni(II), and Cu(II) Complexes of 4′-Phenyl-2,2′:6′,2″-terpyridine: Preparation, Structure, Properties, and Autonomous and pH-Triggered Healing”, Polymers, 16:22 (2024), 3127
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