Abstract:
Novel amphiphilic graft copolymers with various polyester backbone and poly(2-alkyl-2-oxazoline) side chains were synthesized using polyester-type macroinitiators with sulfonyl chloride initiating groups. The obtained graft copolymers exhibit thermoresponsive properties in aqueous solutions in a broad temperature interval.
Citation:
A. N. Blokhin, A. B. Razina, M. P. Kurlykin, A. V. Kashina, A. V. Tenkovtsev, “New thermoresponsive polyester-graft-polyoxazolines based on sulfonyl chloride macroinitiators”, Mendeleev Commun., 30:6 (2020), 799–801
Linking options:
https://www.mathnet.ru/eng/mendc1330
https://www.mathnet.ru/eng/mendc/v30/i6/p799
This publication is cited in the following 6 articles:
Elena Tarabukina, Anna Krasova, Mikhail Kurlykin, Andrey Tenkovtsev, Alexander Filippov, “Conformation and thermoresponsiveness of a graft copolymer at poly-2-isopropyl-2-oxazoline side chains and an aromatic polyester main chain with a short alkylene spacer”, J Polym Res, 32:2 (2025)
Aleksey N. Blokhin, Tatyana Y. Kirila, Alla B. Razina, Serafim V. Rodchenko, Alexander P. Filippov, Andrey V. Tenkovtsev, “Thermosensitive Molecular Brushes With Alternating Polyoxazoline Side Chains: Synthesis, Characterization, and Solubilization Properties”, Journal of Polymer Science, 2024
I. I. Tarasenko, N. N. Zakharova, E. N. Vlasova, E. G. Korzhikova-Vlakh, “A novel thermoresponsive polypeptide: synthesis and characterization”, Mendeleev Commun., 34:3 (2024), 348–350
N.D. Kozina, A.N. Blokhin, T.U. Kirila, A.B. Razina, A.E. Bursian, M.P. Kurlykin, A.P. Filippov, A.V. Tenkovtsev, “Synthesis of novel star-shaped calix[4]arene-based poly(2-oxazoline)s and study of their complexation with curcumin”, Materials Today Communications, 34 (2023), 105403
A. N. Blokhin, T. Yu. Kirila, N. D. Kozina, A. B. Razina, A. P. Filippov, A. V. Tenkovtsev, “Synthesis and hydrodynamic properties of star poly(2-alkyl-2-oxazolines) and poly(2-alkyl-2-oxazines) based on sulfochlorinated calix[4]arene initiator”, Mendeleev Commun., 32:2 (2022), 247–248
T. K. Meleshko, A. B. Razina, N. N. Bogorad, M. P. Kurlykin, A. V. Kashina, I. V. Gofman, A. V. Ten'kovtsev, A. V. Yakimansky, “Synthesis of Poly(ester-graft-methyl methacrylate) on a Macroinitiator with Lateral Sulfonyl Chloride Groups by Atom Transfer Radical Polymerization”, Polym. Sci. Ser. B, 63:4 (2021), 385
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