Abstract:
Borylation of arenes with bis(pinacolato)diboron catalyzed by sterically encumbered NHC platinum complexes proceeds predominantly at ortho-position even in the absence of a directing group (o : m : p ratio up to 10: 3: 1). The similar borylation with pinacolborane would proceed less selectively.
Citation:
S. A. Rzhevskiy, M. A. Topchiy, Yu. D. Golenko, P. S. Gribanov, G. K. Sterligov, N. Yu. Kirilenko, A. A. Ageshina, M. V. Bermeshev, M. S. Nechaev, A. F. Asachenko, “Undirected ortho-selectivity in C–H borylation of arenes catalyzed by NHC platinum(0) complexes”, Mendeleev Commun., 30:5 (2020), 569–571
Linking options:
https://www.mathnet.ru/eng/mendc1254
https://www.mathnet.ru/eng/mendc/v30/i5/p569
This publication is cited in the following 5 articles:
Tongliang Zhou, Greta Utecht-Jarzyńska, Michal Szostak, “Ring-expanded N-heterocyclic carbene (reNHC) complexes: Applications in transition metal catalysis”, Coordination Chemistry Reviews, 512 (2024), 215867
Hajar A. Ali, Mohamed A. Ismail, Abd El-Aziz S. Fouda, Eslam A. Ghaith, “A fruitful century for the scalable synthesis and reactions of biphenyl derivatives: applications and biological aspects”, RSC Adv., 13:27 (2023), 18262
Shouquan Huo, Yumin Li, Handbook of CH-Functionalization, 2022, 1
V.-H. Nguyen, H. T. Phung, D. T. Doan, T. T. Do, “Highly cytotoxic palladium(ii) complexes with 1,2,4-triazole-derived carbene ligands”, Mendeleev Commun., 32:5 (2022), 594–596
S. A. Rzhevskiy, V. N. Bogachev, L. I. Minaeva, G. K. Sterligov, M. S. Nechaev, M. A. Topchiy, A. F. Asachenko, “Efficient synthesis of 3-arylbutadiene sulfones using the Heck–Matsuda reaction”, Mendeleev Commun., 31:4 (2021), 548–549
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