Abstract:
A precursor for the production of azo chromophores, viz. 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate, was prepared and characterized. Its copolymerization with methyl methacrylate was carried out and the copolymerization constants were determined: for 2-hydroxy-3-(N-methyl-N-phenylamino) propyl methacrylate, r1 = 0.50; for methyl methacrylate, r2 = 0.93. The average block lengths of monomers of the same type depending on the composition of the copolymer were estimated.
Keywords:
radical polymerization, methacrylic copolymers, nonlinear optical polymers, comonomer reactivity ratios, probability of bonds formation, copolymer microstructure, 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate.
Citation:
A. I. Gaysin, T. A. Vakhonina, E. O. Yakovleva, M. Yu. Balakina, O. G. Sinyashin, “Copolymers of 2-hydroxy-3-(N-methyl-N-phenylamino)propyl methacrylate with methyl methacrylate and their microstructure”, Mendeleev Commun., 34:3 (2024), 332–334