P. A. Zhmurov, D. V. Dar'in, O. Yu. Bakulina, M. Yu. Krasavin, “One-pot preparation of methyl 2-diazo-3-oxopropionates comprising an aqueous ‘sulfonyl-azide-free’ (SAFE) diazo transfer step”, Mendeleev Commun., 30:3 (2020), 311

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Mendeleev Communications, 2020, Volume 30, Issue 3, Pages 311–312
DOI: https://doi.org/10.1016/j.mencom.2020.05.016 (Mi mendc1180)

This article is cited in 4 scientific papers (total in 4 papers)

Communications

One-pot preparation of methyl 2-diazo-3-oxopropionates comprising an aqueous ‘sulfonyl-azide-free’ (SAFE) diazo transfer step

P. A. Zhmurov, D. V. Dar'in, O. Yu. Bakulina, M. Yu. Krasavin

Institute of Chemistry, St. Petersburg State University, St. Petersburg, Russian Federation

Full-text PDF (169 kB) Citations (4)

DOI: https://doi.org/10.1016/j.mencom.2020.05.016

Graphic abstract: One-pot preparation of methyl 2-diazo-3-oxopropionates comprising an aqueous ‘sulfonyl-azide-free’ (SAFE) diazo transfer step

Abstract: Methyl 2-diazo-3-oxopropionates were obtained by in situ methoxycarbonylation of methyl ketones followed by diazo transfer onto active methylene group of the intermediate β-oxo esters. At the second stage, ‘sulfonyl-azide-free’ (SAFE) diazo transfer protocol in aqueous medium was employed.

Keywords: methoxycarbonylation, β-oxopropionates, diazo transfer, SAFE cocktail, insertion reactions.

Document Type: Article

Language: English

*Supplementary materials:*
		Supplementary_data_1.pdf	(1.8 Mb)

Citation: P. A. Zhmurov, D. V. Dar'in, O. Yu. Bakulina, M. Yu. Krasavin, “One-pot preparation of methyl 2-diazo-3-oxopropionates comprising an aqueous ‘sulfonyl-azide-free’ (SAFE) diazo transfer step”, Mendeleev Commun., 30:3 (2020), 311–312

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https://www.mathnet.ru/eng/mendc/v30/i3/p311

This publication is cited in the following 4 articles:

Citing articles in Google Scholar: Russian citations, English citations
Related articles in Google Scholar: Russian articles, English articles

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