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Mendeleev Communications, 2020, Volume 30, Issue 3, Pages 293–295
DOI: https://doi.org/10.1016/j.mencom.2020.05.010
(Mi mendc1174)
 

This article is cited in 13 scientific papers (total in 13 papers)

Communications

Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate

D. S. Yambulatova, P. A. Petrovbc, Yu. V. Nelyubinaad, A. A. Starikovae, A. A. Pavlovd, D. Y. Aleshind, S. A. Nikolaevskiia, M. A. Kiskina, M. N. Sokolovbc, I. L. Eremenkoad

a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
c Novosibirsk State University, Novosibirsk, Russian Federation
d A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
e Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russian Federation
Abstract: An adduct of ZnII pivalate with N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene has been prepared and characterized by X-ray diffraction analysis, NMR spectroscopy and DFT calculations. The compound preserves mononuclear structure in solution and does not switch the coordination mode from normal to abnormal.
Keywords: N-heterocyclic carbenes, carboxylate complexes, zinc(II), DFT calculations, X-ray crystallography.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (947.9 Kb)


Citation: D. S. Yambulatov, P. A. Petrov, Yu. V. Nelyubina, A. A. Starikova, A. A. Pavlov, D. Y. Aleshin, S. A. Nikolaevskii, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate”, Mendeleev Commun., 30:3 (2020), 293–295
Linking options:
  • https://www.mathnet.ru/eng/mendc1174
  • https://www.mathnet.ru/eng/mendc/v30/i3/p293
  • This publication is cited in the following 13 articles:
    1. A. S. Samulionis, S. N. Melnikov, A. A. Pavlov, A. A. Starikova, N. V. Gogoleva, S. A. Nikolaevskii, M. A. Kiskin, I. L. Eremenko, “Synthesis and Structure of the Mononuclear Zinc Complex with 4-Biphenylcarboxylate Anions and 1,10-Phenanthroline”, J Struct Chem, 65:1 (2024), 63  crossref
    2. I. K. Rubtsova, P. N. Vasilyev, J. K. Voronina, M. A. Shmelev, N. N. Efimov, S. A. Nikolaevskii, I. L. Eremenko, M. A. Kiskin, “Imidazolium Salts with Heterometallic Complex Anions [Co2Li2(Piv)8]2–: Synthesis, Structures, and Magnetic Properties”, Russ J Coord Chem, 50:7 (2024), 523  crossref
    3. S. A. Nikolaevskii, A. A. Starikova, “Quantum Chemical Study of the Structure and Stability of the Adducts of Zn(II) Pivalate with N-Heterocyclic Carbenes”, J Struct Chem, 65:3 (2024), 478  crossref
    4. P. A. Petrov, S. A. Nikolaevskii, E. A. Filippova, N. B. Kompankov, T. S. Sukhikh, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “New Polymorph of 1,3-Bis(2,6-di-isopropylphenyl)-4,5-Dichloroimidazole-2-Ylidene and a Cobalt Complex with this Compound”, J Struct Chem, 65:1 (2024), 117  crossref
    5. I. K. Rubtsova, P. N. Vasilyev, J. K. Voronina, M. A. Shmelev, N. N. Efimov, S. A. Nikolaevskii, I. L. Eremenko, M. A. Kiskin, “Imidazolium Salts with Heterometallic Complex Anions [Co₂Li₂(Piv)₈]²⁻: Synthesis, Structures, and Magnetic Properties”, Koordinacionnaâ himiâ, 50:11 (2024), 787  crossref
    6. S. N. Melnikov, I. K. Rubtsova, S. A. Nikolaevskii, I. L. Eremenko, M. A. Kiskin, “Peculiarities of the Synthesis and Structures of Heterometallic Carboxylate Complexes with {Zn2Ln} and {Zn2Ca} Metal Cores”, Russ J Coord Chem, 50:11 (2024), 873  crossref
    7. P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, A. A. Starikova, T. S. Sukhikh, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Raznoligandnyi anionnyi kompleks pivalata kobalta(II) s mostikovym trimetilsiloksoligandom: sintez, stroenie i mekhanizm formirovaniya”, Žurnal neorganičeskoj himii, 68:9 (2023), 1255  crossref
    8. P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, A. A. Starikova, T. S. Sukhikh, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Heteroleptic Anionic Cobalt(II) Pivalate Complex with a Bridging Trimethylsiloxy Ligand: Synthesis, Structure, and Formation Mechanism”, Russ. J. Inorg. Chem., 68:9 (2023), 1228  crossref
    9. P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, T. S. Sukhikh, A. A. Starikova, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Heteroleptic Cobalt Complexes with Abnormally Coordinated N-Heterocyclic Carbene”, Russ J Coord Chem, 49:7 (2023), 407  crossref
    10. P. A. Petrov, S. A. Nikolaevskii, D. S. Yambulatov, T. S. Sukhikh, A. A. Starikova, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Heteroleptic Cobalt Complexes with Abnormally Coordinated N-Heterocyclic Carbene”, Koordinacionnaâ himiâ, 49:7 (2023), 398  crossref
    11. Debabrata Mukherjee, Comprehensive Organometallic Chemistry IV, 2022, 89  crossref
    12. M. M. Roy, S. R. Baird, M. J. Ferguson, E. Rivard, “Toward N-heterocyclic carbene stabilized zinc sulfides”, Mendeleev Commun., 31:2 (2021), 173–175  mathnet  crossref
    13. D. S. Yambulatov, S. A. Nikolaevskii, M. A. Shmelev, K. A. Babeshkin, D. V. Korchagin, N. N. Efimov, A. S. Goloveshkin, P. A. Petrov, M. A. Kiskin, M. N. Sokolov, I. L. Eremenko, “Heterometallic Coii-Lii carboxylate complexes with N-heterocyclic carbene, triphenylphosphine and pyridine: a comparative study of magnetic properties”, Mendeleev Commun., 31:5 (2021), 624–627  mathnet  crossref
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