Abstract:
The reaction of FeIII and LII pivalates with 1,10-phenanthroline (phen) in toluene simultaneously gives the heteronuclear compounds [Fe2Li(O)(Piv)5(phen)2]·2HPiv and [{Li4(Piv)4(HPiv)2}{Fe2LiO(Piv)5(phen)2}2]·2PhMe with a structural organization uncharacteristic of FeIII and alkali metals. According to X-ray diffraction data, the trinuclear metal oxide moiety {Fe2Li (μ3-O)} forms two nonequivalent complex molecules, which form infinite horizontal chains in the crystal due to stacking interactions between aromatic rings.
Citation:
I. A. Lutsenko, M. A. Kiskin, S. A. Nikolaevskii, Yu. V. Nelyubina, P. V. Primakov, A. S. Goloveshkin, V. K. Imshennik, Yu. V. Maksimov, A. A. Sidorov, I. L. Eremenko, “Nontrivial structural organization of pivalate complexes with the fragment {Fe2Li(μ3-O)}”, Mendeleev Commun., 30:3 (2020), 273–275
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https://www.mathnet.ru/eng/mendc1167
https://www.mathnet.ru/eng/mendc/v30/i3/p273
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