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Mendeleev Communications, 2020, Volume 30, Issue 3, Pages 273–275
DOI: https://doi.org/10.1016/j.mencom.2020.05.003
(Mi mendc1167)
 

This article is cited in 13 scientific papers (total in 13 papers)

Communications

Nontrivial structural organization of pivalate complexes with the fragment {Fe2Li(μ3-O)}

I. A. Lutsenkoa, M. A. Kiskina, S. A. Nikolaevskiia, Yu. V. Nelyubinab, P. V. Primakovbc, A. S. Goloveshkinb, V. K. Imshennikd, Yu. V. Maksimovd, A. A. Sidorova, I. L. Eremenkoab

a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
c Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
d N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
Abstract: The reaction of FeIII and LII pivalates with 1,10-phenanthroline (phen) in toluene simultaneously gives the heteronuclear compounds [Fe2Li(O)(Piv)5(phen)2]·2HPiv and [{Li4(Piv)4(HPiv)2}{Fe2LiO(Piv)5(phen)2}2]·2PhMe with a structural organization uncharacteristic of FeIII and alkali metals. According to X-ray diffraction data, the trinuclear metal oxide moiety {Fe2Li (μ3-O)} forms two nonequivalent complex molecules, which form infinite horizontal chains in the crystal due to stacking interactions between aromatic rings.
Keywords: heterometallic pivalate complexes, iron(III), lithium, 1,10-phenanthroline, crystal structure, Mössbauer spectroscopy.
Document Type: Article
Language: English
Supplementary materials:
Supplementary_data_1.pdf (547.8 Kb)


Citation: I. A. Lutsenko, M. A. Kiskin, S. A. Nikolaevskii, Yu. V. Nelyubina, P. V. Primakov, A. S. Goloveshkin, V. K. Imshennik, Yu. V. Maksimov, A. A. Sidorov, I. L. Eremenko, “Nontrivial structural organization of pivalate complexes with the fragment {Fe2Li(μ3-O)}”, Mendeleev Commun., 30:3 (2020), 273–275
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  • https://www.mathnet.ru/eng/mendc1167
  • https://www.mathnet.ru/eng/mendc/v30/i3/p273
  • This publication is cited in the following 13 articles:
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    2. D. S. Yambulatov, Yu. K. Voronina, S. A. Nikolaevskii, A. I. Poddel'skii, M. A. Kiskin, I. L. Eremenko, “Tetranuclear Heterometallic Iron(II)–Lithium Carboxylates Stabilized by N-Donor Ligands: Synthesis and Structure”, Koordinacionnaâ himiâ, 49:8 (2023), 466  crossref
    3. Evgeniya S. Bazhina, Mikhail A. Kiskin, Konstantin A. Babeshkin, Nikolay N. Efimov, Matvey V. Fedin, Igor L. Eremenko, “Effect of the solvent on the formation of new oxovanadium(IV) complexes with pentafluorobenzoate anions and 1,10-phenanthroline”, Inorganica Chimica Acta, 544 (2023), 121238  crossref
    4. I. A. Lutsenko, Y. A. Tigai, M. A. Shmelev, D. S. Yambulatov, A. S. Zaeva, E. A. Samoylenko, A. V. Khoroshilov, M. A. Kiskin, I. L. Eremenko, “Synthesis, Crystal Structure, and Thermal Behavior of the [Fe(bpy)3]2[Ba(NO3)6] Ionic Complex”, J Struct Chem, 64:12 (2023), 2370  crossref
    5. D. S. Yambulatov, J. K. Voronina, S. A. Nikolaevskii, A. I. Poddel'skii, M. A. Kiskin, I. L. Eremenko, “Tetranuclear Heterometallic Iron(II)–Lithium Carboxylates Stabilized by N-Donor Ligands: Synthesis and Structure”, Russ J Coord Chem, 49:8 (2023), 479  crossref
    6. I. A. Lutsenko, M. A. Kiskin, Ya. A. Tigai, E. V. Volchkova, V. K. Imshennik, S. V. Novichikhin, I. L. Eremenko, “Nontrivial Chemical Assembly of a Molecular Complex with Fe3+ and Li+ Cations”, Russ J Coord Chem, 48:11 (2022), 760  crossref
    7. D. A. Zherebtsov, V. V. Sharutin, M. A. Polozov, S. A. Naifert, K. Radzhakumar, S. A. Adonin, A. A. Osipov, A. I. Lutsenko, “2,4,6-TRIIODIDE-3-AMINOBENZOATE NICKEL COMPLEXES: SYNTHESIS, STRUCTURE AND NONCOVALENT INTERACTIONS IN THE SOLID STATE”, J Struct Chem, 63:11 (2022), 1850  crossref
    8. O. S. Pushikhina, K. R. Volkova, E. V. Karpova, V. A. Tafeenko, M. A. Zakharov, “Synthesis, crystal structure and thermal stability of new copper(II) trichloroacetate complexes”, Mendeleev Commun., 32:2 (2022), 208–211  mathnet  crossref
    9. M. A. Bondarenko, M. I. Rakhmanova, A. S. Novikov, M. N. Sokolov, S. A. Adonin, “Bi- or trinuclear 2-iodobenzoate complexes of Znii: crystal structures and luminescence”, Mendeleev Commun., 32:5 (2022), 585–587  mathnet  crossref
    10. M. A. Bondarenko, S. A Adonin, “CRYSTAL STRUCTURES OF MIXED-LIGAND BINUCLEAR Zn(II) 2-IODOBENZOATE COMPLEXES WITH 4-ETHYL- AND 3-CHLOROPYRIDINE”, J Struct Chem, 62:8 (2021), 1251  crossref
    11. Irina A. Lutsenko, Dmitriy S. Yambulatov, Mikhail A. Kiskin, Yulia V. Nelyubina, Petr V. Primakov, Nikolay N. Efimov, Konstantin A. Babeshkin, Andrey V. Khoroshilov, Yurii V. Maksimov, Sergey V. Novichikhin, Ekaterina M. Zueva, Alexey A. Sidorov, Igor L. Eremenko, “Mono- and tetranuclear Fe(II,III) complexes with primary 1,3-diaminopropane: Synthetic aspects, magnetic properties and thermal behavior”, Polyhedron, 206 (2021), 115354  crossref
    12. I. A. Lutsenko, M. A. Kiskin, D. E. Baravikov, Yu. V. Nelyubina, P. V. Primakov, I. L. Eremenko, “Chemical design of heterometallic carboxylate structures with Fe3+ and Ag+ ions as a rational synthetic approach”, Mendeleev Commun., 31:5 (2021), 628–630  mathnet  crossref
    13. Irina A. Lutsenko, Dmitriy S. Yambulatov, Mikhail A. Kiskin, Yulia V. Nelyubina, Petr V. Primakov, Olga B. Bekker, Oleg A. Levitskiy, Tatiana V. Magdesieva, Vladimir K. Imshennik, Yurii V. Maksimov, Aleksey A. Sidorov, Valery N. Danilenko, Igor L. Eremenko, “Improved In Vitro Antimycobacterial Activity of Trinuclear Complexes Cobalt(II,III) and Iron(III) with 2‐Furoic Acid againstMycolicibacterium smegmatis”, ChemistrySelect, 5:38 (2020), 11837  crossref
    Citing articles in Google Scholar: Russian citations, English citations
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