This article is cited in 13 scientific papers (total in 13 papers)
Focus Article
Radical anion and coordination compounds of polyconjugated molecules:potential organic materials with unusual magnetic, conducting and optical properties
Abstract:
Radical anion salts and coordination complexes of fullerenes, macrocycles and organic dyes obtained by reduction are considered. The reduction transfers an electron to these molecules enabling their participation in magnetic coupling of spins and/or high conductivity as well as modifies essentially their optical properties. Different types of electron transfer between the components have also been observed for these compounds. This review presents new approaches to the syntheses of these salts and complexes as well as their structural and physiochemical properties. Prospects for the development of this area are discussed.
Keywords:
π-conjugated material, organic electronics, fullerene, phthalocyanine, porphyrin, charge transfer complex, radical anion salt, low dimension organic conductor, charge transfer, magnetic ordering of spins.
Document Type:
Article
Language: English
Citation:
D. V. Konarev, “Radical anion and coordination compounds of polyconjugated molecules:potential organic materials with unusual magnetic, conducting and optical properties”, Mendeleev Commun., 30:3 (2020), 249–261
Linking options:
https://www.mathnet.ru/eng/mendc1165
https://www.mathnet.ru/eng/mendc/v30/i3/p249
This publication is cited in the following 13 articles:
P. A. Koutentis, A. Yu. Makarov, O. A. Rakitin, A. V. Zibarev, “Herz chemistry and its applications in small-molecule functional materials science: achievements, challenges, and prospects”, RUSS CHEM REV, 94:1 (2025), RCR5146
Kira D. Krivenko, Alexander F. Shestakov, Maxim A. Faraonov, Alexey V. Kuzmin, Salavat S. Khasanov, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Dmitri V. Konarev, “Complexes of d‐ and f‐metal Ions with a Redox‐Active and Highly Symmetric Truxenone Ligand: Effect of Cations and Coordination on Distortions of Radical Anions and Singlet‐Triplet Transitions in Dianions”, Eur J Inorg Chem, 2025
Michael A. Saley, Emad M. Hamed, Abdelaziz Houmam, “Dissociative Electron Transfer to N‐(Arylthio)phthalimides: Factors Affecting the Formation and Dissociation of Radical Anions”, ChemElectroChem, 11:8 (2024)
Maxim V. Mikhailenko, Vladislav V. Ivanov, Maxim A. Faraonov, Aleksey V. Kuzmin, Salavat S. Khasanov, Ilya A. Yakushev, Natalia N. Breslavskaya, Elena N. Timokhina, Tatiana Yu. Astakhova, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Dmitri V. Konarev, “Effect of nuclearity and reduction state of the central ligand on magnetic properties of hexaazatrinaphthylene-based cobalt(ii) and iron(ii) complexes: from extremely weak to record-breaking antiferromagnetic exchange interaction”, Inorg. Chem. Front., 11:21 (2024), 7563
Maxim V. Mikhailenko, Vladislav V. Ivanov, Maxim A. Faraonov, Aleksey V. Kuzmin, Salavat S. Khasanov, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Dmitri V. Konarev, “Manganese(ii) complexes of hexaazatrinaphthylene and hexaazatrianthracene: synthesis, structure and properties”, New J. Chem., 47:48 (2023), 22339
Maxim V. Mikhailenko, Vladislav V. Ivanov, Alexander F. Shestakov, Aleksey V. Kuzmin, Salavat S. Khasanov, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Dmitri V. Konarev, “Magnetic behavior and ground spin states for coordination {L·[MII(Hal)2]3}3- assemblies (Hal = Cl or I) of radical trianion hexacyanohexaazatriphenylenes (L) with three coordinated high-spin FeII (S = 2) or CoII (S = 3/2) centers”, Dalton Trans., 52:32 (2023), 11222
M. D. Grishin, N. V. Zolotareva, Yu. S. Panova, V. V. Suschev, R. V. Rumyantcev, G. K. Fukin, A. N. Kornev, “2-Thienyl-substituted 3a,6a-diaza-1,4-diphosphapentalene: Synthesis and complexation with 1,2,4,5-tetracyanobenzene”, Mendeleev Commun., 33:5 (2023), 631–634
Maxim V. Mikhailenko, Vladislav V. Ivanov, Alexey V. Kuzmin, Maxim A. Faraonov, Alexander F. Shestakov, Salavat S. Khasanov, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Dmitri V. Konarev, “New HATNA(CN)6 ligand in the design of dianion magnetic assemblies with lanthanides {Cryptand(K+)}2{HATNA(CN)6·3LnIII(TMHD)3}2- (Ln = Gd, Tb and Dy)”, Polyhedron, 228 (2022), 116186
A. El-Denglawey, Marwah Ahmed Alsharif, S. Alfadhli, Abdulrhman M. Alsharari, M.A. Sebak, Essam E. Ali, A.A.A. Darwish, “Nanostructured films of Safranin-T on p-Si as a heterostructure for photovoltaic applications: Electronic and optoelectronic studies”, Physica B: Condensed Matter, 639 (2022), 413986
Jörg Daniels, Florian Weigend, Martin Jansen, “Tracing the Jahn‐Teller Distortion of C60n- in Isostructural Fullerides [M(NH3)7]C60 ⋅ NH3, M=Ba, Sr, K”, Zeitschrift anorg allge chemie, 647:11 (2021), 1132
Abdelaziz Houmam, Emad M. Hamed, Michael A. Saley, “New Insights into the Substituents' Effect on the Formation and Dissociation of Radical Anions: Dissociative Electron Transfer to Arylsulfonylphthalimides”, ChemElectroChem, 8:23 (2021), 4537
Dmitri V. Konarev, Aleksey V. Kuzmin, Salavat S. Khasanov, Alexander F. Shestakov, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Rimma N. Lyubovskaya, “Decacyclene Radical Anions Showing Strong Low‐energy Intramolecular Absorption and Magnetic Coupling of Spins in a Hexagonal Network”, Chemistry — An Asian Journal, 15:17 (2020), 2689
Dmitri V. Konarev, Salavat S. Khasanov, Alexey V. Kuzmin, Maxim V. Mikhailenko, Akihiro Otsuka, Hideki Yamochi, Hiroshi Kitagawa, Rimma N. Lyubovskaya, “Solid‐State Properties of Hexaazatriphenylenehexacarbonitrile HAT(CN)6.- Radical Anions in Crystalline Salts Containing Cryptand(M+) and Crystal Violet Cations”, Chemistry A European J, 26:72 (2020), 17470
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