Abstract:
Treatment of a bulky dbhmp-bian ligand (dbhmp-bian==1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene) by 1 equiv. of LiAlH4 or mixture of 3/4 equiv. LiAlH4 and 1/3 eqiuv. AlCl3 in tetrahydrofuran results in new hydrides [(dbhmp-bian)AlH2(THF)]-[Li(THF)4]+ and (dbhmp-bian)AlH(THF), respectively. Both complexes were characterized by spectroscopic (IR, NMR) and X-ray diffraction methods.
Citation:
M. V. Moskalev, D. A. Razborov, A. A. Bazanov, V. G. Sokolov, T. S. Koptseva, E. V. Baranov, I. L. Fedushkin, “One-step synthesis of new aluminum hydrides bearing a highly sterically hindered acenaphthene-1,2-diimine ligand”, Mendeleev Commun., 30:1 (2020), 94–96
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This publication is cited in the following 14 articles:
M. V. Moskalev, A. A. Skatova, A. A. Bazanov, E. V. Baranov, I. L. Fedushkin, “Reactions of Carbon Dioxide Bound to Aluminum Diimine Hydride with Borane Dimethyl Sulfide and Ammonia”, Russ J Coord Chem, 50:2 (2024), 118
M. V. Moskalev, N. L. Bazyakina, E. V. Baranov, I. L. Fedyushkin, “Aluminum Dihalide Complexes Based on the 1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]Acenaphthene Ligand”, J Struct Chem, 65:9 (2024), 1865
M. V. Moskalev, A. A. Skatova, A. A. Bazanov, E. V. Baranov, I. L. Fedushkin, “Reactions of carbon dioxide bound to aluminum diimine hydride with borane dimethyl sulfide and ammonia”, Koordinacionnaâ himiâ, 50:3 (2024)
Tatyana S. Koptseva, Andrey A. Bazanov, Alexandra A. Skatova, Mikhail V. Moskalev, Evgeny V. Baranov, Igor L. Fedushkin, “Mixed Lithium–Aluminum Hydrides Bearing Ar-Bian Ligands: Reactivity Toward Heteroallenes”, Organometallics, 43:13 (2024), 1438
D. A. Lukina, A. A. Skatova, E. A. Kozlova, I. L. Fedushkin, “Ytterbium Complexes with Redox-Active N,N-Chelating Ligands”, Russ J Gen Chem, 93:S3 (2023), S782
Yu. M. Milekhin, D. N. Sadovnichii, A. A. Koptelov, M. M. Kireenko, S. A. Malinin, “Influence of electron irradiation on the properties of α-aluminum hydride polymorph”, Russ Chem Bull, 71:1 (2022), 44
T. S. Koptseva, M. V. Moskalev, A. A. Skatova, A. A. Bazanov, E. V. Baranov, E. A. Rychagova, S. Yu. Ketkov, I. L. Fedushkin, “Borane reduction of carbon dioxide bound to diimine-supported aluminum hydrides”, Russ Chem Bull, 71:8 (2022), 1626
Tatyana S. Koptseva, Mikhail V. Moskalev, Alexandra A. Skatova, Roman V. Rumyantcev, Igor L. Fedushkin, “Reduction of CO2 with Aluminum Hydrides Supported with Ar-BIAN Radical-Anions (Ar-BIAN = 1,2-Bis(arylimino)acenaphthene)”, Inorg. Chem., 61:1 (2022), 206
M. G. Chegerev, A. A. Starikova, A. G. Starikov, V. I. Minkin, “Computational search for redox isomerism in Ge and Sn bis-chelates with α-diimine ligands”, Mendeleev Commun., 32:1 (2022), 49–51
Mikhail V. Moskalev, Alexandra A. Skatova, Danila A. Razborov, Andrey A. Bazanov, Natalia L. Bazyakina, Vladimir G. Sokolov, Igor L. Fedushkin, “Magnesium and Calcium Complexes of ArBIG‐bian and Their Reactivity towards CO2 (ArBIG‐bian=1,2‐bis[(2,6‐dibenzhydryl‐4‐methylphenyl)imino]acenaphthene)”, Eur J Inorg Chem, 2021:19 (2021), 1890
Mikhail V. Moskalev, Danila A. Razborov, Alexandra A. Skatova, Andrey A. Bazanov, Igor L. Fedushkin, “Alkali Metal Reduction of 1,2‐Bis[(2,6‐dibenzhydryl‐4‐methylphenyl)imino]acenaphthene (ArBIG‐bian) to Radical‐Anion”, Eur J Inorg Chem, 2021:5 (2021), 458
Priyabrata Ghana, Thomas P. Spaniol, Jun Okuda, “Scandium Reduced Arene Complex: Protonation and Reaction with Azobenzene”, Chemistry — An Asian Journal, 16:20 (2021), 3170
Mikhail V. Moskalev, Vladimir G. Sokolov, Tatyana S. Koptseva, Alexandra A. Skatova, Andrey A. Bazanov, Evgenii V. Baranov, Igor L. Fedushkin, “Reactivity of aluminum hydrides supported with sterically hindered acenaphthene-1,2-diimines towards CO2”, Journal of Organometallic Chemistry, 949 (2021), 121972
Daria A. Lukina, Alexandra A. Skatova, Vladimir G. Sokolov, Evgenii V. Baranov, Serhiy Demeshko, Sergey Yu. Ketkov, Igor L. Fedushkin, “Low-coordinate Sm(ii) and Yb(ii) complexes derived from sterically-hindered 1,2-bis(imino)acenaphthene (ArBIG-bian)”, Dalton Trans., 49:41 (2020), 14445
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