Abstract:
The reaction of gold(i) chloride with two molecules of 1,5-diaza-3,7-diphosphacyclooctane derivative causes their reorganization into 16-membered macrocyclic tetraphosphine ligand. The structure of the trinuclear gold(i) complex obtained was confirmed by X-ray analysis. The dynamic equilibrium between dinuclear gold(i) complexes with eight-membered cyclic ligands and the trinuclear gold(i) complex with 16-membered ones has been revealed.
Citation:
I. D. Strelnik, I. R. Dayanova, T. M. Poryvaev, T. P. Gerasimova, I. A. Litvinov, S. A. Katsyuba, E. I. Musina, A. A. Karasik, O. G. Sinyashin, “Rearrangement of two 8-membered 1,5-diaza-3,7-diphosphacyclooctane rings into 16-membered P4N4 ligand on the gold(i) template”, Mendeleev Commun., 30:1 (2020), 40–42
Linking options:
https://www.mathnet.ru/eng/mendc1094
https://www.mathnet.ru/eng/mendc/v30/i1/p40
This publication is cited in the following 7 articles:
Igor D. Strelnik, Tatiana P. Gerasimova, Kseniya A. Karasik, Igor A. Litvinov, Irina R. Dayanova, Kamil D. Ahmadgaleev, Alexey V. Kurenkov, Elvira I. Musina, Andrey A. Karasik, “New classification of cyclic P2N2-ligands predicting bridging and chelate coordination”, Inorganic Chemistry Communications, 172 (2025), 113638
Benedict J. Elvers, Christian Fischer, Carola Schulzke, “Dynamics and Coordination of a P2N2 Ligand – from Twisted Conformation to Chelation”, Chemistry A European J, 30:24 (2024)
A. S. Balueva, E. I. Musina, F. Z. Baimukhametov, G. N. Nikonov, A. T. Gubaidullin, I. A. Litvinov, A. A. Karasik, “Synthesis and Crystal and Molecular Structures of 1,3-Di-p-tolyl-5-(5'-allyl 2'-ethoxybenzyl)-1,3,5-diazaphosphacyclohexane Complexes with Ni(II) and Pt(II) Salts”, Russ J Coord Chem, 48:4 (2022), 189
Dmitry V. Moiseev, Brian R. James, “Phospha-Mannich reactions of RPH2, R2PH, and R3P”, Phosphorus, Sulfur, and Silicon and the Related Elements, 197:4 (2022), 327
Irina R. Dayanova, Aliia V. Shamsieva, Igor D. Strelnik, Tatiana P. Gerasimova, Ilya E. Kolesnikov, Robert R. Fayzullin, Daut R. Islamov, Alina F. Saifina, Elvira I. Musina, Evamarie Hey-Hawkins, Andrey A. Karasik, “Assembly of Heterometallic AuICu2I2 Cores on the Scaffold of NPPN-Bridging Cyclic Bisphosphine”, Inorg. Chem., 60:7 (2021), 5402
Yu. S. Spiridonova, I. D. Strelnik, E. I. Musina, E. Hey-Hawkins, I. A. Litvinov, A. A. Karasik, “New Gold(I) Complexes with 1,5-Diaza-3,7-Diphosphacyclooctanes: Synthesis and Structures”, Russ J Coord Chem, 46:7 (2020), 477
Yulia S. Spiridonova, Yulia A. Nikolaeva, Anna S. Balueva, Elvira I. Musina, Igor A. Litvinov, Igor D. Strelnik, Vera V. Khrizanforova, Yulia G. Budnikova, Andrey A. Karasik, “Synthesis and Structure of Iron (II) Complexes of Functionalized 1,5-Diaza-3,7-Diphosphacyclooctanes”, Molecules, 25:17 (2020), 3775
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