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Mendeleev Communications, 2021, Volume 31, Issue 5, Pages 628–630
DOI: https://doi.org/10.1016/j.mencom.2021.09.012 (Mi mendc1004) 		 
This article is cited in 3 scientific papers (total in 3 papers)

Communications

Chemical design of heterometallic carboxylate structures with Fe3+ and Ag+ ions as a rational synthetic approach

I. A. Lutsenkoa, M. A. Kiskina, D. E. Baravikova, Yu. V. Nelyubinab, P. V. Primakovb, I. L. Eremenkoa

a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
Full-text PDF (662 kB) Citations (3)
DOI: https://doi.org/10.1016/j.mencom.2021.09.012
Abstract: Solid phase thermolysis of pivalate complex [Fe3O(Piv)6(HPiv)3]Piv generates the [Fe3O(Piv)6]+ complex cation due to a deficiency of ligands in the coordination sphere of the metal ions. Crystallization of [Fe3O(Piv)6]+ from THF–EtOH leads to the heteroleptic complex [Fe3O(Piv)6(THF)(EtOH)(OH)] · 0.5 THF · 0.5 H2O in 69% yield, while the reaction of [Fe3O(Piv)6]+ with AgNO3 in toluene results in the complex [Fe4Ag4O2(Piv)12] · 2 PhMe with a rare combination of FeIII and AgI atoms. Crystal structures of the two new complexes have been established.
Keywords: iron complex, solid phase thermolysis, heteroleptic complex, silver, crystal structure.
Document Type: Article
Language: English


Citation: I. A. Lutsenko, M. A. Kiskin, D. E. Baravikov, Yu. V. Nelyubina, P. V. Primakov, I. L. Eremenko, “Chemical design of heterometallic carboxylate structures with Fe3+ and Ag+ ions as a rational synthetic approach”, Mendeleev Commun., 31:5 (2021), 628–630
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    • This publication is cited in the following 3 articles:
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