Matematicheskaya Biologiya i Bioinformatika
RUS  ENG    JOURNALS   PEOPLE   ORGANISATIONS   CONFERENCES   SEMINARS   VIDEO LIBRARY   PACKAGE AMSBIB  
General information
Latest issue
Archive
Impact factor

Search papers
Search references

RSS
Latest issue
Current issues
Archive issues
What is RSS



Mat. Biolog. Bioinform.:
Year:
Volume:
Issue:
Page:
Find






Personal entry:
Login:
Password:
Save password
Enter
Forgotten password?
Register


Matematicheskaya Biologiya i Bioinformatika, 2017, Volume 12, Issue 2, Pages 466–486
DOI: https://doi.org/10.17537/2017.12.466
(Mi mbb307)
 

Mathematical Modeling

Computer aided molecular modeling of the piezoelectric properties of ferroelectric composites on the base of polyvinylidene fluoride with graphene and graphene oxide

A. V. Bystrovaa, E. V. Paramonovaa, I. K. Bdikinbc, M. V. Silibinb, D. V. Karpinskybd, X. J. Menge, V. S. Bystrovab

a Institute of Mathematical Problems of Biology RAS – the Branch of Keldysh Institute of Applied Mathematics, Pushchino, Russia
b National Research University «MIET», Moscow, Russia
c Department of Mechanical Eng. & TEMA, University of Aveiro, Aveiro, Portugal
d Scientific-Practical Materials Research Centre of NAS of Belarus, Minsk, Belarus
e Shanghai Institute of Technical Physics, ChAS, Shanghai, China
References:
Abstract: Molecular modeling of ferroelectric composites containing polyvinylidene fluoride (PVDF), graphene (G) and/or graphene oxide (GO), was performed using the semi-empirical quantum approximation PM3 in the HyperChem software package. The piezoelectric properties of the composites were analyzed and compared with the experimental data obtained for thin films containing poly(vinylidene-fluoride-trifluoroethylene) with graphene oxide (P (VDF-TrFE)/GO). A qualitative agreement was obtained between the simulation results and the experimental measurements of the piezoelectric coefficient, its decrease in the presence of G or GO was revealed. When models containing one or more layers of graphene with 54 carbon atoms were investigated, it was found that the average piezoelectric coefficient was reduced to -9.8 pm/V for the one-sided PVDF/G model and to -18.98 pm/V for the two-sided sandwich model G/PVDF/G in compare with the calculated piezoelectric coefficient for pure PVDF (-42.2 pm/V). After computer modeling for models incorporating one or more layers of 96 carbon atoms in the oxide graphene, it was found that the piezoelectric coefficient was reduced to a value of -14.6 pm/V for a one-sided PVDF / GO model and to a value of -29.8 pm/V for a two-sided sandwich model GO/ PVDF/GO compared to the piezoelectric coefficient for pure PVDF.
Key words: ferroelectric polymers, piezoelectrics, computer molecular modeling, graphene and graphene oxide, composites.
Funding agency Grant number
Russian Science Foundation 16-19-10112
Fundação para a Ciência e a Tecnologia UID/EMS/00481/2013
Russian Foundation for Basic Research 16-51-53017_ГФЕН_а
15-01-04924_а
National Natural Science Foundation of China
Received 20.11.2017, Published 08.12.2017
Document Type: Article
UDC: 530.1: 537.226.33: 541.1: 577:681.2
Language: Russian
Citation: A. V. Bystrova, E. V. Paramonova, I. K. Bdikin, M. V. Silibin, D. V. Karpinsky, X. J. Meng, V. S. Bystrov, “Computer aided molecular modeling of the piezoelectric properties of ferroelectric composites on the base of polyvinylidene fluoride with graphene and graphene oxide”, Mat. Biolog. Bioinform., 12:2 (2017), 466–486
Citation in format AMSBIB
\Bibitem{BysParBdi17}
\by A.~V.~Bystrova, E.~V.~Paramonova, I.~K.~Bdikin, M.~V.~Silibin, D.~V.~Karpinsky, X.~J.~Meng, V.~S.~Bystrov
\paper Computer aided molecular modeling of the piezoelectric properties of ferroelectric composites on the base of polyvinylidene fluoride with graphene and graphene oxide
\jour Mat. Biolog. Bioinform.
\yr 2017
\vol 12
\issue 2
\pages 466--486
\mathnet{http://mi.mathnet.ru/mbb307}
\crossref{https://doi.org/10.17537/2017.12.466}
Linking options:
  • https://www.mathnet.ru/eng/mbb307
  • https://www.mathnet.ru/eng/mbb/v12/i2/p466
  • Citing articles in Google Scholar: Russian citations, English citations
    Related articles in Google Scholar: Russian articles, English articles
     
      Contact us:
     Terms of Use  Registration to the website  Logotypes © Steklov Mathematical Institute RAS, 2024