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This article is cited in 4 scientific papers (total in 4 papers)
Physical science of materials
Structure and optical properties of the silver/polyacrylonitrile nanocomposites
M. A. Kudryashova, A. I. Mashina, A. V. Nezhdanova, A. A. Logunova, T. A. Grachevaa, T. A. Kuz'michevaa, G. Chidichimob, G. De Filpob a Lobachevsky State University of Nizhny Novgorod
b Università degli Studi della Calabria, ITALY
Abstract:
Small-angle X-ray scattering is used to prove the formation of silver nanoparticles with sizes of 5–11 nm in siver/polyacrylonitrile nanocomposites synthesized via photopolymerization of a mixture containing silver, acrylonitrile, and photoinitiator. Optical spectra of nanocomposites obtained under different conditions are studied. The absorption spectra exhibit maxima at wavelengths of 420–450 nm related to the surface plasmon resonance of silver nanoparticles. IR spectra of the nanocomposites prove the formation of polyacrylonitrile in the course of the photopolymerization of monomer. The formation of metal nanoimpurities in polymer matrix leads to an increase in the intensity of photoluminescence and Raman scattering of polyacrylonitrile.
Received: 03.11.2015
Citation:
M. A. Kudryashov, A. I. Mashin, A. V. Nezhdanov, A. A. Logunov, T. A. Gracheva, T. A. Kuz'micheva, G. Chidichimo, G. De Filpo, “Structure and optical properties of the silver/polyacrylonitrile nanocomposites”, Zhurnal Tekhnicheskoi Fiziki, 86:11 (2016), 80–85; Tech. Phys., 61:11 (2016), 1684–1688
Linking options:
https://www.mathnet.ru/eng/jtf6393 https://www.mathnet.ru/eng/jtf/v86/i11/p80
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