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This article is cited in 4 scientific papers (total in 4 papers)
Physics of nanostructures
Formation mechanism of argon clathrates with carbon dendrites
M. P. Danilaeva, E. M. Zuevabc, E. A. Bogoslova, M. S. Pudovkinc, Yu. E. Pol'skiia a Kazan National Research Technical University named after A. N. Tupolev
b A. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences
c Kazan (Volga Region) Federal University
Abstract:
The formation mechanism of argon clathrates with carbon dendrites obtained in the plasma of an atmospheric-pressure gas discharge has been studied. It has been shown that the formation of these clathrates is due to the difference between characteristic times: the lifetime of molecules surrounding argon atoms and the time of C–C bonding. It has been noted that argon clathrates with carbon dendrites can form only if a number of conditions are met: formation of molecular traps in the discharge, provision of a sufficiently low temperature at the center of the arc discharge, and the presence of active carbon particles arising from plasma decomposition of hydrocarbon precursors. Whether or not these conditions are met depends primarily on the composition of the initial hydrocarbon mixture and discharge current density, as follows from experimental data.
Received: 24.07.2017
Citation:
M. P. Danilaev, E. M. Zueva, E. A. Bogoslov, M. S. Pudovkin, Yu. E. Pol'skii, “Formation mechanism of argon clathrates with carbon dendrites”, Zhurnal Tekhnicheskoi Fiziki, 88:6 (2018), 883–887; Tech. Phys., 63:6 (2018), 857–861
Linking options:
https://www.mathnet.ru/eng/jtf5897 https://www.mathnet.ru/eng/jtf/v88/i6/p883
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