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This article is cited in 2 scientific papers (total in 2 papers)
Physical science of materials
Role of silicon carbide in arc discharge synthesis of higher fullerenes
I. E. Kareeva, A. E. Dutlovb, V. P. Bubnova a Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
b Lomonosov Moscow State University
Abstract:
The effects that the presence of silicon atoms in the zone of electric arc used for evaporation of graphite electrodes has on the efficiency of formation of higher fullerenes C$_{76}$, C$_{78}$, С$_{80}$, С$_{82}$, C$_{84}$, С$_{86}$, etc., are studied. Optimization of the evaporation conditions and the use of composite graphite electrodes containing silicon carbide, the additive, in the range of 0 to 6.3 wt% enables us to produce soot with the fullerene content at up to 15.5 wt% in a soot extract and, at the time, achieve a high net fullerene yield of 10.5% of the soot weight.
Keywords:
fullerenes, higher fullerenes, silicon carbide, electric arc synthesis, HPLC.
Received: 25.03.2019 Revised: 17.04.2019 Accepted: 21.07.2019
Citation:
I. E. Kareev, A. E. Dutlov, V. P. Bubnov, “Role of silicon carbide in arc discharge synthesis of higher fullerenes”, Zhurnal Tekhnicheskoi Fiziki, 90:1 (2020), 110–114; Tech. Phys., 65:1 (2020), 102–106
Linking options:
https://www.mathnet.ru/eng/jtf5415 https://www.mathnet.ru/eng/jtf/v90/i1/p110
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