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Zhurnal Tekhnicheskoi Fiziki, 2021, Volume 91, Issue 2, Pages 222–231
DOI: https://doi.org/10.21883/JTF.2021.02.50355.208-20
(Mi jtf5073)
 

This article is cited in 17 scientific papers (total in 17 papers)

Theoretical and Mathematical Physics

Peaks of hydrogen thermal desorption: simulation and interpretation

Yu. V. Zaikaa, E. K. Kostikovaa, Yu. S. Nechaevb

a Institute of Applied Mathematical Research of the Karelian Research Centre RAS, Petrozavodsk
b I. P. Bardin Central Research Institute of Iron and Steel Industry
Abstract: Different models of hydrogen thermal desorption peaks have been analyzed. The model of volume-averaged concentration dynamics with a continuum parameter makes it possible to integrally take into consideration the dominance of limiting factors: diffusion and recombination of atoms into desorbing molecules. An analytical symmetry criterion for peaks versus the method of expanding a composed spectrum into a series of Gaussian curves is suggested. Modifications of (i) the Kissinger method to estimate the activation energy of desorption in experiments with several material heating rates and (ii) a procedure for solving the inverse problem of unimodal peak parametrical identification from one heat rate are presented. Comparison with the diffusion model with dynamic boundary conditions has been carried out. It has been shown that local peaks may arise not only because of release of hydrogen atoms with different binding energies captured by volume traps, but also because of interaction between volume and surface processes and heat-induced surface structure modifications. The parameters of deuterium thermal desorption from ISO-880U graphite have been estimated.
Keywords: hydrogen thermodesorption, TDS peaks modeling, parametric identification.
Funding agency Grant number
Russian Foundation for Basic Research 18-29-19149 мк
This study was financially supported by the Russian Foundation for Basic Research, grant no. 18-29-19149 mk.
Received: 19.06.2020
Revised: 20.08.2020
Accepted: 25.08.2020
English version:
Technical Physics, 2021, Volume 66, Issue 2, Pages 210–220
DOI: https://doi.org/10.1134/S1063784221020250
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: Yu. V. Zaika, E. K. Kostikova, Yu. S. Nechaev, “Peaks of hydrogen thermal desorption: simulation and interpretation”, Zhurnal Tekhnicheskoi Fiziki, 91:2 (2021), 222–231; Tech. Phys., 66:2 (2021), 210–220
Citation in format AMSBIB
\Bibitem{ZaiKosNec21}
\by Yu.~V.~Zaika, E.~K.~Kostikova, Yu.~S.~Nechaev
\paper Peaks of hydrogen thermal desorption: simulation and interpretation
\jour Zhurnal Tekhnicheskoi Fiziki
\yr 2021
\vol 91
\issue 2
\pages 222--231
\mathnet{http://mi.mathnet.ru/jtf5073}
\crossref{https://doi.org/10.21883/JTF.2021.02.50355.208-20}
\elib{https://elibrary.ru/item.asp?id=44885086}
\transl
\jour Tech. Phys.
\yr 2021
\vol 66
\issue 2
\pages 210--220
\crossref{https://doi.org/10.1134/S1063784221020250}
\scopus{https://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85102079783}
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  • This publication is cited in the following 17 articles:
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