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Zhurnal Tekhnicheskoi Fiziki, 2021, Volume 91, Issue 6, Pages 964–969
DOI: https://doi.org/10.21883/JTF.2021.06.50866.284-20
(Mi jtf4992)
 

Physical science of materials

A crossover in methanol fuel cell with modified graphene membrane

A. F. Vyatkina, E. V. Gerasimovab, O. V. Kononenkoa

a Institute of Microelectronics Technology and High-Purity Materials RAS
b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
Abstract: The possibility of modifying the nafion direct alcohol fuel cell proton-exchange membrane by monolayer graphene by hot pressing has been demonstrated. It is shown that this modification can reduce the permeability of the membrane on methanol while maintaining a high proton conductivity membrane, but with the long operation of the membrane without additional protection of the barrier layer formed in this way, it is detached. With a Nafion/graphene/Nafion membrane, the formed graphene layer is sufficiently protected to reduce the methanol crossover and increase the power of the single methanol fuel cell by 2 times.
Keywords: graphene, crossover, membrane, permeability, fuel cell.
Funding agency Grant number
Ministry of Education and Science of the Russian Federation АААА-А19-119061890019-5
0070-2019-0003
Received: 08.10.2020
Revised: 15.12.2020
Accepted: 16.12.2020
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: A. F. Vyatkin, E. V. Gerasimova, O. V. Kononenko, “A crossover in methanol fuel cell with modified graphene membrane”, Zhurnal Tekhnicheskoi Fiziki, 91:6 (2021), 964–969
Citation in format AMSBIB
\Bibitem{VyaGerKon21}
\by A.~F.~Vyatkin, E.~V.~Gerasimova, O.~V.~Kononenko
\paper A crossover in methanol fuel cell with modified graphene membrane
\jour Zhurnal Tekhnicheskoi Fiziki
\yr 2021
\vol 91
\issue 6
\pages 964--969
\mathnet{http://mi.mathnet.ru/jtf4992}
\crossref{https://doi.org/10.21883/JTF.2021.06.50866.284-20}
\elib{https://elibrary.ru/item.asp?id=46468638}
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