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Zhurnal Tekhnicheskoi Fiziki, 2021, Volume 91, Issue 6, Pages 922–927
DOI: https://doi.org/10.21883/JTF.2021.06.50860.316-20
(Mi jtf4986)
 

To the 125th anniversary of Academician N.N. Semenov

Ferrocene-photocatalized polymerization of cyanate esters for 3D printing

E. S. Sorina, D. A. Gurovb, G. V. Malkovb, G. F. Novikovab

a Lomonosov Moscow State University, Faculty of Fundamental Physical and Chemical Engineering
b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
Abstract: The kinetic studies of photodissociation of ferrocene in the oligomer of bisphenol A dicyanate were done using photospectroscopy. Thermograms of polymerization of the bisphenol A dicyanate oligomer in the presence of photodissociated ferrocene were also obtained. Based on kinetic calculations and analysis of thermograms, conclusion has been made regarding the possibility and promising use of a system based on the oligomer bisphenol A dicyanate and ferrocene for 3D printing.
Keywords: cyanate ester, ferrocene, kinetics, photodissociation, polymerization, photospectroscopy, differential calorimetry.
Funding agency Grant number
Ministry of Education and Science of the Russian Federation АААА-А19-119070790003-7
This study was performed in the framework of state assignment no. AAAA-A19-119070790003-7.
Received: 15.11.2020
Revised: 06.01.2021
Accepted: 19.01.2021
English version:
Technical Physics, 2021, Volume 66, Issue 12, Pages 1324–1329
DOI: https://doi.org/10.1134/S1063784221060177
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: E. S. Sorin, D. A. Gurov, G. V. Malkov, G. F. Novikov, “Ferrocene-photocatalized polymerization of cyanate esters for 3D printing”, Zhurnal Tekhnicheskoi Fiziki, 91:6 (2021), 922–927; Tech. Phys., 66:12 (2021), 1324–1329
Citation in format AMSBIB
\Bibitem{SorGurMal21}
\by E.~S.~Sorin, D.~A.~Gurov, G.~V.~Malkov, G.~F.~Novikov
\paper Ferrocene-photocatalized polymerization of cyanate esters for 3D printing
\jour Zhurnal Tekhnicheskoi Fiziki
\yr 2021
\vol 91
\issue 6
\pages 922--927
\mathnet{http://mi.mathnet.ru/jtf4986}
\crossref{https://doi.org/10.21883/JTF.2021.06.50860.316-20}
\elib{https://elibrary.ru/item.asp?id=46468632}
\transl
\jour Tech. Phys.
\yr 2021
\vol 66
\issue 12
\pages 1324--1329
\crossref{https://doi.org/10.1134/S1063784221060177}
\scopus{https://www.scopus.com/record/display.url?origin=inward&eid=2-s2.0-85126754281}
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