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NEXAFS and FTIR spectroscopy of Co-doped SrBi$_2$Nb$_2$O$_9$
Nadezhda A. Zhuka, Elena U. Ipatovab, Boris A. Makeevc, Sergey V. Nekipelovd, Dmitriy S. Beznosikove, Lubov V. Rychkovaa a Pitirim Sorokin Syktyvkar State University, Syktyvkar, Russian Federation
b Institute of Chemistry of the Komi Scientific Center Ural Branch RAS, Syktyvkar, Russian Federation
c Institute of Geology of the Komi Scientific Center Ural Branch RAS, Syktyvkar, Russian Federation
d Institute of Physics and Mathematics of the Komi Science Center UB RAS, Syktyvkar, Russian Federation
e Federal State Unitary Enterprise «General Radio Frequency Centre»
Syktyvkar, Russian Federation
Abstract:
The solid-phase ceramic method was used to synthesize cobalt-containing solid solutions based on SrBi$_2$Nb$_2$O$_9$. NEXAFS (Near Edge X-ray Absorption Fine Structure) and IR spectroscopy were used to study the electronic state of cobalt atoms in solid cross-links with a layered perovskite-like structure. It was found that cobalt atoms are in high-spin states of Co(III) and, mainly, Co(II) in an octahedral oxygen environment.
Keywords:
Aurivillius phases, IR spectroscopy, NEXAFS, cobalt.
Received: 26.04.2021 Received in revised form: 20.08.2021 Accepted: 22.10.2021
Citation:
Nadezhda A. Zhuk, Elena U. Ipatova, Boris A. Makeev, Sergey V. Nekipelov, Dmitriy S. Beznosikov, Lubov V. Rychkova, “NEXAFS and FTIR spectroscopy of Co-doped SrBi$_2$Nb$_2$O$_9$”, J. Sib. Fed. Univ. Math. Phys., 15:1 (2022), 5–12
Linking options:
https://www.mathnet.ru/eng/jsfu969 https://www.mathnet.ru/eng/jsfu/v15/i1/p5
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Abstract page: | 70 | Full-text PDF : | 48 | References: | 19 |
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