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Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki, 2023, Volume 117, Issue 8, Pages 604–611
DOI: https://doi.org/10.31857/S1234567823080074
(Mi jetpl6921)
 

This article is cited in 3 scientific papers (total in 3 papers)

CONDENSED MATTER

Electrostatic and Van der Waals interactions of nanoparticles in electrolytes

A. V. Filippovabc, V. M. Starovd

a State Research Center of the Russian Federation Troitsk Institute for Innovation and Fusion Research, Troitsk, Moscow, 108840 Russia
b Joint Institute for High Temperatures, Russian Academy of Sciences, Moscow, 125412 Russia
c Moscow Institute of Physics and Technology (National Research University), Dolgoprudnyi, Moscow region, 141701 Russia
d Department of Chemical Engineering, Loughborough University, Loughborough, LE11 3TU, United Kingdom
References:
Abstract: The electrostatic interaction between nanoparticles caused by the overlapping of double electric layers and the van der Waals interaction caused by quantum and thermodynamic fluctuations of electromagnetic fields are considered. The linearized Poisson–Boltzmann equation for particles with a fixed electric potential on their surface is used in the case of the electrostatic interaction. An exact solution of the problem has been obtained both for identical particles and for particles with strongly different sizes. The screening of static fluctuations and the retardation of electromagnetic fields for the dispersion part of the van der Waals interaction have been taken into account. The total interaction energy of two particles has been calculated for ion concentrations in an electrolyte from 10$^{-6}$ to 10$^{-2}$ mol/L and sizes of nanoparticles from 1 to 10$^3$ nm. It has been found that the van der Waals force exceeds the screened electrostatic repulsive force at high concentrations of the electrolyte from 10$^{-3}$ to 10$^{-2}$ mol/L at both small and large interparticle distances.
Funding agency Grant number
Russian Science Foundation 22-22-01000
European Union NanoPaInt Marie Curie
European Space Agency MAP EVAPORATION
This work was supported by the Russian Science Foundation (project no. 22-22-01000, A.V. Filippov) and by the European Space Agency (projects NanoPaInt Marie Curie, EC, and MAP EVAPORATION, V. M. Starov).
Received: 15.03.2023
Revised: 15.03.2023
Accepted: 16.03.2023
English version:
Journal of Experimental and Theoretical Physics Letters, 2023, Volume 117, Issue 8, Pages 598–605
DOI: https://doi.org/10.1134/S002136402360074X
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: A. V. Filippov, V. M. Starov, “Electrostatic and Van der Waals interactions of nanoparticles in electrolytes”, Pis'ma v Zh. Èksper. Teoret. Fiz., 117:8 (2023), 604–611; JETP Letters, 117:8 (2023), 598–605
Citation in format AMSBIB
\Bibitem{FilSta23}
\by A.~V.~Filippov, V.~M.~Starov
\paper Electrostatic and Van der Waals interactions of nanoparticles in electrolytes
\jour Pis'ma v Zh. \`Eksper. Teoret. Fiz.
\yr 2023
\vol 117
\issue 8
\pages 604--611
\mathnet{http://mi.mathnet.ru/jetpl6921}
\crossref{https://doi.org/10.31857/S1234567823080074}
\edn{https://elibrary.ru/wfdptc}
\transl
\jour JETP Letters
\yr 2023
\vol 117
\issue 8
\pages 598--605
\crossref{https://doi.org/10.1134/S002136402360074X}
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  • https://www.mathnet.ru/eng/jetpl/v117/i8/p604
  • This publication is cited in the following 3 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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