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Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki, 2019, Volume 109, Issue 9, Pages 605–609
DOI: https://doi.org/10.1134/S0370274X19090078
(Mi jetpl5890)
 

This article is cited in 8 scientific papers (total in 8 papers)

CONDENSED MATTER

Argentite-acanthite transformation in silver sulfide as a disorder-order transition

S. I. Sadovnikov, A. I. Gusev

Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia
Full-text PDF (343 kB) Citations (8)
References:
Abstract: An alternative model has been proposed for the phase transition from cubic argentite $\beta$-Ag$_2$S to monoclinic acanthite $\alpha$-Ag$_2$S in silver sulfide as a disorder-order transition. It has been shown that, as the temperature decreases below the transition temperature $T_{\mathrm{trans}}$, $\mathrm{S}$ atoms equiprobably occupying the sites of the body centered cubic (bcc) nonmetal sublattice of argentite are concentrated at four sites of the monoclinic nonmetal sublattice, whereas the other sites remain vacant. A disorder-order transition channel including three superstructure vectors of $\mathbf{k}_9$ and $\mathbf{k}_4$ stars has been determined. The distribution function of sulfur atoms in monoclinic acanthite $\alpha$-Ag$_2$S has been calculated. It has been shown that displacements of sulfur atoms distort the bcc nonmetal sublattice of argentite, forming a monoclinic lattice, where silver atoms are spaced by quite large distances and occupy their crystallographic positions with a probability of $1$. The region of allowed values of the long-range order parameters $\eta_9$ and $\eta_4$ for the model monoclinic ordered phase $\alpha$-Ag$_2$S has been determined.
Received: 26.02.2019
Revised: 18.03.2019
Accepted: 25.03.2019
English version:
Journal of Experimental and Theoretical Physics Letters, 2019, Volume 109, Issue 9, Pages 584–588
DOI: https://doi.org/10.1134/S0021364019090145
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: S. I. Sadovnikov, A. I. Gusev, “Argentite-acanthite transformation in silver sulfide as a disorder-order transition”, Pis'ma v Zh. Èksper. Teoret. Fiz., 109:9 (2019), 605–609; JETP Letters, 109:9 (2019), 584–588
Citation in format AMSBIB
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  • This publication is cited in the following 8 articles:
    Citing articles in Google Scholar: Russian citations, English citations
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