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Pis'ma v Zhurnal Èksperimental'noi i Teoreticheskoi Fiziki, 2018, Volume 108, Issue 4, Pages 230–235
DOI: https://doi.org/10.1134/S0370274X18160026 (Mi jetpl5675) 		 
This article is cited in 2 scientific papers (total in 2 papers)

CONDENSED MATTER

Atomic and electronic structures of metal-rich noncentrosymmetric ZrO$_x$

V. A. Gritsenkoabc, T. V. Perevalovbc, V. A. Volodinbc, V. N. Kruchininc, A. K. Gerasimovac, I. P. Prosvirind

a Novosibirsk State Technical University, Novosibirsk, Russia
b Novosibirsk State University, Novosibirsk, Russia
c Rzhanov Institute of Semiconductor Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
d Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
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DOI: https://doi.org/10.1134/S0370274X18160026
Abstract: The atomic and electronic structures of metal-rich noncentrosymmetric zirconium oxide synthesized by the ion beam sputtering of a metallic target in an oxygen atmosphere has been studied by X-ray photoelectron spectroscopy, Raman scattering, spectral ellipsometry, and quantum-chemical simulation. It has been established that ZrO$_{x<2}$ consists of ZrO$_2$, metallic Zr, and zirconium suboxides ZrO$_y$. The stoichiometry parameter of ZrO$_y$ has been estimated. It has been shown that the optical properties of ZrO$_{x<2}$ are determined by metallic Zr. A model of fluctuation of the width of the band gap and a potential for electrons and holes in ZrO$_{x<2}$ based on spatial fluctuations of the chemical composition has been proposed.
Funding agency Grant number
Ministry of Education and Science of the Russian Federation 0306-2016-0004
Received: 04.06.2018
Revised: 03.07.2018
English version:
Journal of Experimental and Theoretical Physics Letters, 2018, Volume 108, Issue 4, Pages 226–230
DOI: https://doi.org/10.1134/S002136401816004X
Bibliographic databases:
Document Type: Article
Language: Russian
Citation: V. A. Gritsenko, T. V. Perevalov, V. A. Volodin, V. N. Kruchinin, A. K. Gerasimova, I. P. Prosvirin, “Atomic and electronic structures of metal-rich noncentrosymmetric ZrO$_x$”, Pis'ma v Zh. Èksper. Teoret. Fiz., 108:4 (2018), 230–235; JETP Letters, 108:4 (2018), 226–230
Citation in format AMSBIB
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    • This publication is cited in the following 2 articles:
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